An Unusual Reduction Route of 2,4,6-Trinitrobenzoic Acid under Conditions of Aqueous-Phase Hydrogenation over Pd/Sibunit Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

An Unusual Reduction Route of 2,4,6-Trinitrobenzoic Acid under Conditions of Aqueous-Phase Hydrogenation over Pd/Sibunit Catalyst Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2016, Volume: 65, Number: 6, Pages: 1535-1540 Pages count : 6 DOI: 10.1007/s11172-016-1479-8

Tags

2,4,6-trinitrobenzoic acid, catalytic hydrogenation, palladium catalyst, cyclohexane-1,3,5-trione trioxime

Authors

Mironenko R.M. ^1,2 , Belskaya O.B. ^1,3 , Talzi V.P. ¹ , Rodionov V.A. ¹ , Sysolyatin S.V. ⁴ , Likholobov V.A. ^1,3,5

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, 54 ul. Neftezavodskaya, 644040 Omsk, Russian Federation
2	Dostoevsky Omsk State University, 55a prosp. Mira, 644077 Omsk, Russian Federation
3	Omsk State Technical University, 11 prosp. Mira, 644050 Omsk, Russian Federation.
4	Institute for Problems of Chemical and Energetic Technologies,Siberian Branch of the Russian Academy of Sciences, 1 ul. Sotsialisticheskaya, 659322 Biysk, Altai Krai, Russian Federation
5	Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, 15 prosp. K. Marksa, 644024 Omsk, Russian Federation.

Funding (1)

Russian Foundation for Basic Research

16-03-00601 (АААА-А16-116021950037-7)

For the first time it was established that the catalytic hydrogenation of 2,4,6-trinitrobenzoic acid to 1,3,5-triaminobenzene can proceed via the formation of aromatic hydroxyamines and cyclohexane-1,3,5-trione trioxime. As a result of aqueousphase hydrogenation of sodium salt of 2,4,6-trinitrobenzoic acid in the presence of 5%Pd/Sibunit catalyst at a temperature of 323 K and pressure of 0.5 MPa, a trioxime in high yield (about 70 %) was obtained. Due to high selectivity to cyclohexane-1,3,5-trione trioxime the catalytic hydrogenation of sodium salt of 2,4,6-trinitrobenzoic acid can be considered as a new method for its synthesis.

Mironenko R.M. , Belskaya O.B. , Talzi V.P. , Rodionov V.A. , Sysolyatin S.V. , Likholobov V.A.
An Unusual Reduction Route of 2,4,6-Trinitrobenzoic Acid under Conditions of Aqueous-Phase Hydrogenation over Pd/Sibunit Catalyst
Russian Chemical Bulletin. 2016. V.65. N6. P.1535-1540. DOI: 10.1007/s11172-016-1479-8 WOS Scopus РИНЦ ANCAN OpenAlex

Мироненко Р.М. , Бельская О.Б. , Талзи В.П. , Родионов В.А. , Сысолятин С.В. , Лихолобов В.А.
Необычный путь восстановления 2,4,6-тринитробензойной кислоты в условиях аквафазного гидрирования на катализаторе Pd/Сибунит
Известия Академии наук. Серия химическая. 2016. №6. С.1535-1540. РИНЦ

Submitted:	Jan 28, 2016
Accepted:	Apr 4, 2016
Published print:	Jun 1, 2016
Published online:	Feb 22, 2017

Web of science:	WOS:000395522500012
Scopus:	2-s2.0-85013408032
Elibrary:	29479769
Chemical Abstracts:	2017:338265
Chemical Abstracts (print):	166:266134
OpenAlex:	W2590357158

DB	Citing
Web of science	12
Scopus	11
Elibrary	12
OpenAlex	12