Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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| Output data | Year: 2016, Volume: 65, Number: 11, Pages: 2712-2717 Pages count : 6 DOI: 10.1007/s11172-016-1640-4 | ||||
| Tags | polyvinyl chloride, carbon materials, conjugated polymers, polyvinylenes, waste recycling. | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-33-00018 (114123040010) |
Abstract:
A method for carbon materials synthesis based on polyvinyl chloride has been proposed.
Method includes polymer dehydrochlorination by alkali with carbonrich conjugated structures
(polyvinylenes) formation and its subsequent carbonization at relatively low temperatures.
Raman and 13C NMR spectroscopy and transmission electron microscopy show that thermal
treatment of the resulting polyvinylenes up to 400 °C leads to the formation of amorphous
carbon material with chlorine contain less than 0.5 wt.%. These results can be used to develop
dioxinfree technology of utilization of polyvinyl chloride and its wastes.
Cite:
Solodovnichenko V.S.
, Kryazhev Y.G.
, Arbuzov A.B.
, Talzi V.P.
, Antonicheva N.V.
, Drozdov V.A.
, Zapevalova E.S.
, Likholobov V.A.
Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials
Russian Chemical Bulletin. 2016. V.65. N11. P.2712-2717. DOI: 10.1007/s11172-016-1640-4 WOS Scopus РИНЦ OpenAlex ANCAN
Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials
Russian Chemical Bulletin. 2016. V.65. N11. P.2712-2717. DOI: 10.1007/s11172-016-1640-4 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Солодовниченко В.С.
, Кряжев Ю.Г.
, Арбузов А.Б.
, Талзи В.П.
, Антоничева Н.В.
, Дроздов В.А.
, Запевалова Е.С.
, Лихолобов В.А.
Поливинилхлорид как предшественник для низкотемпературного синтеза углеродных материалов
Известия Академии наук. Серия химическая. 2016. №11. С.2712-2717. РИНЦ
Поливинилхлорид как предшественник для низкотемпературного синтеза углеродных материалов
Известия Академии наук. Серия химическая. 2016. №11. С.2712-2717. РИНЦ
Dates:
| Submitted: | May 25, 2016 |
| Accepted: | Aug 15, 2016 |
| Published print: | Nov 1, 2016 |
| Published online: | May 17, 2017 |
Identifiers:
| ≡ Web of science: | WOS:000401572700023 |
| ≡ Scopus: | 2-s2.0-85019199718 |
| ≡ Elibrary: | 31027609 |
| ≡ OpenAlex: | W2615246677 |
| ≡ Chemical Abstracts: | 2017:802414 |
| ≡ Chemical Abstracts (print): | 167:6329 |