A Study of Pd/C Catalysts in the Liquid-phase Hydrogenation of 1,3,5-Trinitrobenzene and 2,4,6-Trinitrobenzoic Acid. Selection of Hydrogenation Conditions for Selective Production of 1,3,5-Triaminobenzene | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Study of Pd/C Catalysts in the Liquid-phase Hydrogenation of 1,3,5-Trinitrobenzene and 2,4,6-Trinitrobenzoic Acid. Selection of Hydrogenation Conditions for Selective Production of 1,3,5-Triaminobenzene Full article

Conference

International Conference on Oil and Gas Engineering
25-30 Apr 2015 , Omsk

Journal

Procedia Engineering
ISSN: 1877-7058

Output data

Year: 2016, Volume: 152, Pages: 110-115 Pages count : 6 DOI: 10.1016/j.proeng.2016.07.640

Tags

catalytic hydrogenation; 1,3,5-Trinitrobenzene; 2,4,6-Trinitrobenzoic acid; 1,3,5-Triaminobenzene; Pd/C

Authors

Belskaya O.B. ^1,2 , Mironenko R.M. ^1,3 , Talsi V.P. ¹ , Rodionov V.A. ¹ , Sysolyatin S.V. ⁴ , Likholobov V.A. ^1,2,5

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, 54, Neftezavodskaya St., 644040 Omsk, Russian Federation
2	Omsk State Technical University, 11, Mira Pr., 644050 Omsk, Russian Federation
3	F.M. Dostoevsky Omsk State University, 55a, Mira Pr., 644077 Omsk, Russian Federation
4	Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, 1, Socialisticheskaya St., 659322 Biysk, Altai krai, Russian Federation
5	Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, 15, Marksa Pr., 644024 Omsk, Russian Federation

Funding (1)

Russian Foundation for Basic Research

16-03-00601 (АААА-А16-116021950037-7)

The liquid-phase hydrogenation of aromatic trinitro compounds was studied at atmospheric and elevated pressure and a temperature of 50–70 °C. It was shown that at atmospheric pressure, irrespective of the solvent type (water or acetic anhydride), a complete reduction of the nitro groups of 2,4,6-trinitrobenzoic acid to amino groups does not occur; the intermediate products of hydrogenation and the products of secondary transformations are present in the solution. An increase in pressure to 5 bars ensures a complete hydrogenation of 2,4,6-trinitrobenzoic acid and 1,3,5-trinitrobenzene with the formation of 1,3,5-triaminobenzene.

Belskaya O.B. , Mironenko R.M. , Talsi V.P. , Rodionov V.A. , Sysolyatin S.V. , Likholobov V.A.
A Study of Pd/C Catalysts in the Liquid-phase Hydrogenation of 1,3,5-Trinitrobenzene and 2,4,6-Trinitrobenzoic Acid. Selection of Hydrogenation Conditions for Selective Production of 1,3,5-Triaminobenzene

Procedia Engineering. 2016. V.152. P.110-115. DOI: 10.1016/j.proeng.2016.07.640 WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Published print:	Jan 1, 2016
Published online:	Aug 10, 2016

Web of science:	WOS:000383945400017
Scopus:	2-s2.0-84985963113
Elibrary:	27575614
Chemical Abstracts:	2016:1379976
Chemical Abstracts (print):	165:353620
OpenAlex:	W2492464285

DB	Citing
Web of science	14
Scopus	13
Elibrary	14
OpenAlex	14