Effective Pd/C Catalyst for Chlorobenzene and Hexachlorobenzene Hydrodechlorination by Direct Pyrolysis of Sawdust Impregnated with Palladium Nitrate Full article
| Journal |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2016, Volume: 77, Pages: 37-41 Pages count : 5 DOI: 10.1016/j.catcom.2016.01.013 | ||||
| Tags | Pd catalyst Sawdust Hydrodechlorination Hexachlorobenzene Chlorobenzene Pyrolysis | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-33-00018 (114123040010) |
Abstract:
Two Pd/C catalysts were prepared by pyrolysis of Pd(NO3)2 impregnated sawdust. At equal pyrolysis time slow ramping with shorter isothermal heating resulted in 0.9 wt.% Pd/C-S1 sample comprising carbon support with some oxygen-containing moieties and Pd0 with 2.6 nm average particle size (APS) partially decorated with carbon shell, whereas fast temperature ramping and long isothermal heating provided 0.6 wt.% Pd/C-S2 containing Pd0 with 3.7 nm APS, with larger fraction of carbon decorated particles. Pd/C-S1 is slightly more efficient than Pd/C-S2 in gas phase chlorobenzene hydrodechlorination to benzene at 100–250 °C. Only Pd/C-S1 provides hexachlorobenzene hydrodechlorination in liquid phase due to lower APS and probably smaller PdCx content.
Cite:
Klokov S.V.
, Lokteva E.S.
, Golubina E.V.
, Maslakov K.I.
, Levanov A.V.
, Chernyak S.A.
, Likholobov V.A.
Effective Pd/C Catalyst for Chlorobenzene and Hexachlorobenzene Hydrodechlorination by Direct Pyrolysis of Sawdust Impregnated with Palladium Nitrate
Catalysis Communications. 2016. V.77. P.37-41. DOI: 10.1016/j.catcom.2016.01.013 WOS Scopus РИНЦ ANCAN OpenAlex
Effective Pd/C Catalyst for Chlorobenzene and Hexachlorobenzene Hydrodechlorination by Direct Pyrolysis of Sawdust Impregnated with Palladium Nitrate
Catalysis Communications. 2016. V.77. P.37-41. DOI: 10.1016/j.catcom.2016.01.013 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 8, 2015 |
| Accepted: | Jan 15, 2016 |
| Published online: | Jan 16, 2016 |
| Published print: | Mar 5, 2016 |
Identifiers:
| Web of science: | WOS:000371186900009 |
| Scopus: | 2-s2.0-84955244485 |
| Elibrary: | 26824522 |
| Chemical Abstracts: | 2016:139613 |
| Chemical Abstracts (print): | 164:225550 |
| OpenAlex: | W2286563652 |