Oxidation of N-Isopropyl Phosphonomethyl Glycine with Hydrogen Peroxide Catalyzed by Carbon-Supported Gold Nanoparticles ArticleGenre_short.SHORT_COMMUNICATION
| Journal |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2019, Volume: 121, Pages: 57-61 Pages count : 5 DOI: 10.1016/j.catcom.2018.12.012 | ||
| Tags | Gold nanoparticles; CarbonN-isopropyl glyphosate; Hydrogen peroxide; Oxidative dealkylation | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0008 |
| 2 | Russian Foundation for Basic Research | 16-29-10691 |
Abstract:
Oxidation of N-isopropyl glyphosate with aqueous hydrogen peroxide catalyzed by Au nanoparticles supported on the quasi-graphitic mesoporous carbon materials proceeds efficiently with glyphosate (N-phosphonomethyl glycine) formation. Conditions for N-isopropyl glyphosate selective dealkylation yielding glyphosate with high conversion (100%) and selectivity (79.3%) were found. The catalyst selectivity to the N-phosphonomethyl glycine depends on the Au dispersion.
Cite:
Yushchenko D.Y.
, Simonov P.A.
, Khlebnikova T.B.
, Pai Z.P.
, Bukhtiyarov V.I.
Oxidation of N-Isopropyl Phosphonomethyl Glycine with Hydrogen Peroxide Catalyzed by Carbon-Supported Gold Nanoparticles
Catalysis Communications. 2019. V.121. P.57-61. DOI: 10.1016/j.catcom.2018.12.012 WOS Scopus РИНЦ РИНЦ AN OpenAlex
Oxidation of N-Isopropyl Phosphonomethyl Glycine with Hydrogen Peroxide Catalyzed by Carbon-Supported Gold Nanoparticles
Catalysis Communications. 2019. V.121. P.57-61. DOI: 10.1016/j.catcom.2018.12.012 WOS Scopus РИНЦ РИНЦ AN OpenAlex
Dates:
| Submitted: | Sep 10, 2018 |
| Accepted: | Dec 17, 2018 |
| Published online: | Dec 27, 2018 |
| Published print: | Mar 5, 2019 |
Identifiers:
| Web of science: | WOS:000458708600012 |
| Scopus: | 2-s2.0-85059312415 |
| Elibrary: | 38658825 | 41793453 |
| Chemical Abstracts: | 2019:47962 |
| OpenAlex: | W2908309332 |