Dimethylsulfoxide as a Media for One-Stage Synthesis of the Fe3O4-Based Ferrofluids with a Controllable Size Distribution | Sciact - CRIS-system of Boreskov Institute of Catalysis

Dimethylsulfoxide as a Media for One-Stage Synthesis of the Fe3O4-Based Ferrofluids with a Controllable Size Distribution Full article

Journal

Materials Chemistry and Physics
ISSN: 0254-0584 , E-ISSN: 1879-3312

Output data

Year: 2019, Volume: 225, Pages: 292-297 Pages count : 6 DOI: 10.1016/j.matchemphys.2019.01.003

Tags

Ferrofluid; Magnetite nanoparticles; One-step synthesis; Superparamagnetic nanoparticles; Ferromagnetic resonance

Authors

Kirillov V.L. ¹ , Yakushkin S.S. ¹ , Balaev D.A. ² , Dubrovskiy A.A. ² , Semenov S.V. ² , Knyazev Yu.V. ² , Bayukov O.A. ² , Velikanov D.A. ² , Yatsenko D.A. ¹ , Martyanov O.N. ¹

Affiliations

1	Boreskov Institute of Catalysis, Russian Academy of Sciences, Siberian Branch, Novosibirsk, 630090, Russia
2	Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia

Funding (1)

Russian Science Foundation

17-12-01111

The ultrafine (d = 4 nm) magnetite ferrofluid with a narrow nanoparticle size distribution has been synthesized in one stage at room temperature from a solution of iron(II) and (III) chlorides in dimethylsulfoxide (DMSO) with the propylene epoxide admixture. This is the first example of obtaining a stable concentrated ultrafine magnetite/DMSO ferrofluid at room temperature. X-ray diffraction, transmission electron microscopy, ferromagnetic resonance, Mössbauer spectroscopy, and magnetostatic study have been used to elucidate the role of DMSO and the H2O/DMSO ratio in the formation of a stable colloid with a desired nanoparticle size. The initial stages of the magnetite nanoparticles formation have been investigated by the ferromagnetic resonance technique.

Kirillov V.L. , Yakushkin S.S. , Balaev D.A. , Dubrovskiy A.A. , Semenov S.V. , Knyazev Y.V. , Bayukov O.A. , Velikanov D.A. , Yatsenko D.A. , Martyanov O.N.
Dimethylsulfoxide as a Media for One-Stage Synthesis of the Fe3O4-Based Ferrofluids with a Controllable Size Distribution
Materials Chemistry and Physics. 2019. V.225. P.292-297. DOI: 10.1016/j.matchemphys.2019.01.003 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Aug 21, 2018
Accepted:	Jan 1, 2019
Published online:	Jan 4, 2019
Published print:	Mar 1, 2019

Web of science:	WOS:000463847900040
Scopus:	2-s2.0-85060051682
Elibrary:	38651883
Chemical Abstracts:	2019:55744
OpenAlex:	W2908414032

DB	Citing
Scopus	12
Web of science	11
Elibrary	13
OpenAlex	13