Synthesis of Perfluoroalkyl(Methoxy)Borates and -Boranes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis of Perfluoroalkyl(Methoxy)Borates and -Boranes Full article

Journal

Main Group Metal Chemistry
ISSN: 0792-1241 , E-ISSN: 2191-0219

Output data

Year: 2009, Volume: 32, Number: 3, Pages: 109-114 Pages count : 6 DOI: 10.1515/MGMC.2009.32.3.109

Authors

Adonin Nicolay Yu. ¹ , Bardin Vadim V. ² , Frohn Hermann-Josef ³

Affiliations

1	G.K. Boreskov Institute of Catalysis SB RAS, Lavrent 'ev Ave. 5, 630090 Novosibirsk, Russia
2	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrent 'ev Ave. 9, 630090 Novosibirsk, Russia
3	Department of Chemistry, Inorganic Chemistry, University of Duisburg-Essen, Lotharstr. 1, D-47048 Duisburg, Germany

Interaction of lithium perfluoroalkyltrimethoxyborates, Li[CnF2n+1B(OMe)3] (n=3, 4, 6), with ClSiMe3 results in formation of the corresponding esters СnF2n+1B(OMe)2 in 93-95% yields. They are sufficiently stable both CH2Cl2 and etherical solvents (ether, THF) and react with C2F2Li to give Li[(CnF2n+1)(C2F5)B(OMe)2]. Metathesis of the latter with KF leads to corresponding potassium salts.

Adonin N.Y. , Bardin V.V. , Frohn H-J.
Synthesis of Perfluoroalkyl(Methoxy)Borates and -Boranes
Main Group Metal Chemistry. 2009. V.32. N3. P.109-114. DOI: 10.1515/MGMC.2009.32.3.109 WOS Scopus РИНЦ ANCAN OpenAlex

Published print:	Jun 1, 2009
Published online:	Mar 16, 2011

Web of science:	WOS:000274081400001
Scopus:	2-s2.0-76149129732
Elibrary:	41743139
Chemical Abstracts:	2010:188855
Chemical Abstracts (print):	153:116307
OpenAlex:	W2320437571

DB	Citing
Web of science	5
Scopus	5
Elibrary	5
OpenAlex	4