Synthesis and Properties of Perfluoroalkenylboronic Acids and Some of their Derivatives | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis and Properties of Perfluoroalkenylboronic Acids and Some of their Derivatives Full article

Journal

Main Group Metal Chemistry
ISSN: 0792-1241 , E-ISSN: 2191-0219

Output data

Year: 2009, Volume: 32, Number: 3, Pages: 153-159 Pages count : 7 DOI: 10.1515/MGMC.2009.32.3.153

Authors

Adonin Nicolay Yu. ¹ , Bardin Vadim V. ² , Frohn Hermann-Josef ³

Affiliations

1	G.K. Boreskov Institute of Catalysis SB RAS, Lavrent'ev Ave. 5, 630090 Novosibirsk, Russia
2	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrent'ev Ave. 9, 630090 Novosibirsk, Russia
3	Department of Chemistry, Inorganic Chemistry, University of Duisburg-Essen, Lotharstr. 1, D-47048 Duisburg, Germany

Lithium perfluoroalkenyltrimethoxyborates were prepared and characterised by NMR spectroscopy. These compounds possess the properties inherent in both organic and inorganic boron-containing compounds. Li[XCF=CFB(OMe)3] (X=F, cis-CF3, trans-CF3) react with I2 to give corresponding 1-iodopolyfluoroalkenes in 30-50 % yields. Interaction of Li[XCF=CFB(OMe)3] with ClSiMe3, followed by working up with XCF-CFLi leads to formation of lithium bis(perfluoroalkenyl)dimethoxyborates. Reaction of Li[XCF=CF)nB(OMe)4-n] with K[HF2] in aqueous HF gives corresponding potassium perfluoroalkenylfluoroborates, K[(XCF-СF)nBF4].

Adonin N.Y. , Bardin V.V. , Frohn H-J.
Synthesis and Properties of Perfluoroalkenylboronic Acids and Some of their Derivatives
Main Group Metal Chemistry. 2009. V.32. N3. P.153-159. DOI: 10.1515/MGMC.2009.32.3.153 WOS Scopus РИНЦ ANCAN OpenAlex

Published print:	Jun 1, 2009
Published online:	Mar 16, 2011

Web of science:	WOS:000274081400004
Scopus:	2-s2.0-76149096878
Elibrary:	41743101
Chemical Abstracts:	2010:188858
Chemical Abstracts (print):	153:116308
OpenAlex:	W2316490389

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Web of science	5
Scopus	5
Elibrary	6
OpenAlex	5