The Liquid Phase Catalytic Hydrogenation of Furfural to Furfuryl Alcohol | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Liquid Phase Catalytic Hydrogenation of Furfural to Furfuryl Alcohol Full article

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2019, Volume: 329, Pages: 142-148 Pages count : 7 DOI: 10.1016/j.cattod.2018.12.036

Tags

Furfural; Furfuryl alcohol; Hydrogenation; Palladium catalyst; Hypercrosslinked polystyrene

Authors

Salnikova Ksenia E. ^1,2 , Matveeva Valentina G. ^1,2 , Larichev Yurii V. ^3,4 , Bykov Alexey V. ¹ , Demidenko Galina N. ¹ , Shkileva Irina P. ¹ , Sulman Mikhail G. ¹

Affiliations

1	Tver State Technical University, Department of Biotechnology and Chemistry, A. Nikitin str., 22, 170026 Tver, Russia
2	Tver State University, Regional Technological Centre, Zhelyabova str., 33, 170100 Tver, Russia
3	Boreskov Institute of Catalysis, 5 Academician Lavrentiev Avenue, 630090 Novosibirsk, Russia
4	Novosibirsk State University, 2 Pirogov Street, 630090 Novosibirsk, Russia

Funding (2)

1	Russian Science Foundation	18-19-00240
2	Russian Foundation for Basic Research	18-58-80008

We report the hydrogenation of furfural (FF) to furfuryl alcohol (FA) with Pd-containing catalysts stabilized by hypercrosslinked polystyrene (HPS). FF is one of the major ingredients of biooil produced by biomass pyrolysis, while FA is a source of value-added chemicals, thus, creating an effective path from biomass to important compounds. Different palladium precursors (PdCl2(CH3CN)2, Pd(CH3COO)2) were used for the catalysts synthesis. The nature of the precursor influences the size of palladium nanoparticles. The TEM and SAXS data showed that when using PdCl2(CH3CN)2, a monomodal distribution of particles size with mean diameter 5.4 ± 1.2 nm was observed, whereas for Pd(CH3COO)2, multimodal particle size distribution with the mean particle sizes up to 13.8 ± 5.4 nm was observed. The comparison of the catalytic activities of Pd-containing catalysts indicated that the more disperse sample of palladium showed higher values of FF conversion and selectivity to FA because of small particles.

Salnikova K.E. , Matveeva V.G. , Larichev Y.V. , Bykov A.V. , Demidenko G.N. , Shkileva I.P. , Sulman M.G.
The Liquid Phase Catalytic Hydrogenation of Furfural to Furfuryl Alcohol
Catalysis Today. 2019. V.329. P.142-148. DOI: 10.1016/j.cattod.2018.12.036 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 24, 2018
Accepted:	Dec 17, 2018
Published online:	Dec 19, 2018
Published print:	Jun 1, 2019

Web of science:	WOS:000462764600017
Scopus:	2-s2.0-85059675979
Elibrary:	38642843
Chemical Abstracts:	2019:110015
Chemical Abstracts (print):	170:403067
OpenAlex:	W4376596042

DB	Citing
Scopus	46
Web of science	42
Elibrary	48
OpenAlex	6