Prereforming of Arctic Diesel Fuel into Syngas Full article
Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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Output data | Year: 2018, Volume: 10, Number: 4, Pages: 321-327 Pages count : 7 DOI: 10.1134/s207005041804013x | ||||||
Tags | diesel, syngas, prereforming, nickel, magnesium oxide | ||||||
Authors |
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Affiliations |
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Funding (1)
1 | The Ministry of Education and Science of the Russian Federation | 14.607.21.0149 (RFMEFI60716X0149) |
Abstract:
The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.
Cite:
Samoilov A.V.
, Kirillov V.A.
, Shigarov A.B.
, Brayko A.S.
, Potemkin D.I.
, Shoinkhorova T.B.
, Snytnikov P.V.
, Uskov S.I.
, Pechenkin A.A.
, Belyaev V.D.
, Sobyanin V.A.
Prereforming of Arctic Diesel Fuel into Syngas
Catalysis in Industry. 2018. V.10. N4. P.321-327. DOI: 10.1134/s207005041804013x WOS Scopus РИНЦ OpenAlex
Prereforming of Arctic Diesel Fuel into Syngas
Catalysis in Industry. 2018. V.10. N4. P.321-327. DOI: 10.1134/s207005041804013x WOS Scopus РИНЦ OpenAlex
Original:
Самойлов А.В.
, Кириллов В.А.
, Шигаров А.Б.
, Брайко А.С.
, Потемкин Д.И.
, Шойнхорова Т.Б.
, Снытников П.В.
, Усков С.И.
, Печенкин А.А.
, Беляев В.Д.
, Собянин В.А.
Предриформинг арктического дизельного топлива в синтез-газ
Катализ в промышленности. 2018. Т.18. №3. С.41-47. DOI: 10.18412/1816-0387-2018-3-41-47 РИНЦ AN OpenAlex
Предриформинг арктического дизельного топлива в синтез-газ
Катализ в промышленности. 2018. Т.18. №3. С.41-47. DOI: 10.18412/1816-0387-2018-3-41-47 РИНЦ AN OpenAlex
Dates:
Submitted: | Mar 19, 2018 |
Published print: | Oct 1, 2018 |
Published online: | Jan 14, 2019 |
Identifiers:
Web of science: | WOS:000455594600008 |
Scopus: | 2-s2.0-85060173753 |
Elibrary: | 38664568 |
OpenAlex: | W2910450751 |