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Prereforming of Arctic Diesel Fuel into Syngas Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2018, Volume: 10, Number: 4, Pages: 321-327 Pages count : 7 DOI: 10.1134/s207005041804013x
Tags diesel, syngas, prereforming, nickel, magnesium oxide
Authors Samoilov A. V. 1 , Kirillov V. A. 1,2 , Shigarov A. B. 1,2 , Brayko A. S. 1 , Potemkin D. I. 1,3 , Shoinkhorova T. B. 1 , Snytnikov P. V. 1,2 , Uskov S. I. 1 , Pechenkin A. A. 1 , Belyaev V. D. 1,2 , Sobyanin V. A. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 UNICAT LLC, Novosibirsk, 630090 Russia
3 Novosibirsk State University, Novosibirsk, 630090 Russia

Funding (1)

1 The Ministry of Education and Science of the Russian Federation 14.607.21.0149 (RFMEFI60716X0149)

Abstract: The possibility of using arctic low-sulfur diesel fuel for the production of syngas suitable for solid-oxide fuel cells (SOFSs) in a single stage via the prereforming reaction over Ni-MgO structured catalysts based on a highly porous cellular foam material (HPCFM) made of nickel is demonstrated. Catalysts with mass compositions (wt %) 10.7NiO–10MgO/HPCFM and 20NiO–10MgO/HPCFM are prepared, and their properties in the prereforming of arctic diesel fuel at 550°C are studied. The microstructure of the coating of these catalysts is studied via transmission electron microscopy (TEM) before and after the reaction. The resistance of these prereforming catalysts to carbonization is revealed to be the key factor influencing their stability under operation. The kinetic parameters of this reaction are determined. The obtained results could be helpful in creating power generation units based on fuel cells operating on arctic diesel fuel under the conditions of the Far North.
Cite: Samoilov A.V. , Kirillov V.A. , Shigarov A.B. , Brayko A.S. , Potemkin D.I. , Shoinkhorova T.B. , Snytnikov P.V. , Uskov S.I. , Pechenkin A.A. , Belyaev V.D. , Sobyanin V.A.
Prereforming of Arctic Diesel Fuel into Syngas
Catalysis in Industry. 2018. V.10. N4. P.321-327. DOI: 10.1134/s207005041804013x WOS Scopus РИНЦ OpenAlex
Original: Самойлов А.В. , Кириллов В.А. , Шигаров А.Б. , Брайко А.С. , Потемкин Д.И. , Шойнхорова Т.Б. , Снытников П.В. , Усков С.И. , Печенкин А.А. , Беляев В.Д. , Собянин В.А.
Предриформинг арктического дизельного топлива в синтез-газ
Катализ в промышленности. 2018. Т.18. №3. С.41-47. DOI: 10.18412/1816-0387-2018-3-41-47 РИНЦ AN OpenAlex
Dates:
Submitted: Mar 19, 2018
Published print: Oct 1, 2018
Published online: Jan 14, 2019
Identifiers:
Web of science: WOS:000455594600008
Scopus: 2-s2.0-85060173753
Elibrary: 38664568
OpenAlex: W2910450751
Citing:
DB Citing
Scopus 3
Web of science 3
Elibrary 4
OpenAlex 3
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