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XAFS Study of a Au/Al2O3 Catalytic Nanosystem Doped by Ce and Ce-Zr Oxides Full article

Conference XVII International Synchrotron Radiation Conference
15-20 Jun 2008 , Новосибирск
Journal Nuclear Instruments and Methods in Physics Research Section A
ISSN: 0168-9002
Output data Year: 2009, Volume: 603, Number: 1-2, Pages: 185-187 Pages count : 3 DOI: 10.1016/j.nima.2009.03.004
Tags EXAFS, Gold catalytic system, Local structure, Nanoparticle, XANES, XPS, XRD
Authors Kriventsov V.V. 1 , Simakova I.L. 1 , Simakov A.V. 2 , Smolentseva E. 2 , Castillon F. 2 , Estrada M. 3 , Vargas E. 4 , Yakimchuk E.P. 1 , Ivanov D.P. 1 , Aksenov D.G. 1 , Andreev D.V. 1 , Novgorodov B.N. 1 , Kochubey D.I. 1 , Fuentes S. 2
Affiliations
1 Boreskov Institute of Catalysis, Pr. Ak. Lavrentyeva, 5, Novosibirsk 630090, Russia
2 Centro de Nanociencias y Nanotecnologia, UNAM, Ensenada, BC, Mexico
3 Posgrado en Fisica de Materiales, CICESE, Ensenada, BC, Mexico
4 Posgrado en Ciencia e Ingenierıa, Area Nanotecnologıa, UABC, Ensenada, BC, Mexico

Funding (8)

1 Russian Foundation for Basic Research 06-03-33005
2 Russian Foundation for Basic Research 08-03-01150
3 Russian Foundation for Basic Research 08-03-91758
4 Russian Foundation for Basic Research 08-03-92502
5 Russian Foundation for Basic Research 09-03-01012
6 National Autonomous University of Mexico 50547-Q
7 National Autonomous University of Mexico IN 110208
8 National Autonomous University of Mexico IN 120706-3

Abstract: This work is devoted to a structural study of the finely dispersed nanosized gold species supported on nanosized mixed oxides prepared by the sol–gel method. An analysis of the XANES (Au-L3) spectra has revealed mainly Au3+ cations located on the oxide matrix surface in distorted octahedral coordination for the catalysts reduced at 150 °C. For the catalysts reduced at 300 °C, a highly distorted metallic gold species has been mainly found, within the method limitation. The synthesized catalysts have also been characterized by transmission electron microscopy (TEM), BET, X-ray diffraction (XRD) and XPS.
Cite: Kriventsov V.V. , Simakova I.L. , Simakov A.V. , Smolentseva E. , Castillon F. , Estrada M. , Vargas E. , Yakimchuk E.P. , Ivanov D.P. , Aksenov D.G. , Andreev D.V. , Novgorodov B.N. , Kochubey D.I. , Fuentes S.
XAFS Study of a Au/Al2O3 Catalytic Nanosystem Doped by Ce and Ce-Zr Oxides
Nuclear Instruments and Methods in Physics Research Section A. 2009. V.603. N1-2. P.185-187. DOI: 10.1016/j.nima.2009.03.004 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Mar 9, 2009
Published print: May 11, 2009
Identifiers:
Web of science: WOS:000266760800056
Scopus: 2-s2.0-65549127598
Elibrary: 13603989
Chemical Abstracts: 2009:569804
Chemical Abstracts (print): 152:154800
OpenAlex: W2018495520
Citing:
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Web of science 8
Scopus 8
Elibrary 10
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