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Preparation of Betulone Via Betulin Oxidation Over Ru Nanoparticles Deposited on Graphitic Carbon Nitride Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2019, Том: 149, Номер: 3, Страницы: 723-732 Страниц : 10 DOI: 10.1007/s10562-018-02649-8
Ключевые слова Betulin oxidation; Carbon nitride; Ruthenium; Betulone
Авторы Shcherban N.D. 1,2 , Mäki-Arvela P. 2 , Aho A. 2 , Sergiienko S.А. 3 , Skoryk M.A. 4,5 , Kolobova E. 6 , Simakova I.L. 7 , Eränen K. 2 , Smeds A. 2 , Hemming J. 2 , Murzin D.Yu. 2
Организации
1 L.V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 pr. Nauky, Kiev 03028, Ukraine
2 Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, 20500 Åbo/Turku, Finland
3 National University of Science and Technology MISiS, Leninskii pr. 4, 119049 Moscow, Russia
4 NanoMedTeсh LLC, 68 Gorkogo str., Kiev, Ukraine
5 G.V. Kurdyumov Institute for Metal Physics, N.A.S. of Ukraine, 36 Academician Vernadskiy av., Kiev 03680, Ukraine
6 Research School of Chemistry & Applied Biomedical Sciences, Tomsk Polytechnic University, Lenin Avenue 30, Tomsk 634050, Russia
7 Boreskov Institute of Catalysis, Lavrentieva ave. 5, Novosibirsk, Russia

Информация о финансировании (3)

1 Åbo Akademi University
2 Министерство образования и науки Российской Федерации К2-2018-013
3 Государственный фонд фундаментальных исследований Украины

Реферат: Derivatives of betulin obtained by oxidation have broad pharmacological applications, demonstrating anti-inflammatory, antioxidant, hepatoprotective, and anticancer activity. Ru supported catalysts based on graphitic carbon nitride or N-doped carbon were prepared via a mild reduction of the initial Ru precursor with hydrazine. These catalysts along with Ru supported on carbon nanofibers and a mesoporous carbon support Sibunit were studied in catalytic oxidation of betulin. Ru/carbon nitride demonstrated catalytic activity in betulin oxidation higher than Ru/N-doped carbon (conversion of betulin up to ca. 70% and 30%, respectively). Selectivity to different oxidation products was dependent on the properties of the carbon supports.
Библиографическая ссылка: Shcherban N.D. , Mäki-Arvela P. , Aho A. , Sergiienko S.А. , Skoryk M.A. , Kolobova E. , Simakova I.L. , Eränen K. , Smeds A. , Hemming J. , Murzin D.Y.
Preparation of Betulone Via Betulin Oxidation Over Ru Nanoparticles Deposited on Graphitic Carbon Nitride
Catalysis Letters. 2019. V.149. N3. P.723-732. DOI: 10.1007/s10562-018-02649-8 WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 5 июл. 2018 г.
Принята к публикации: 9 дек. 2018 г.
Опубликована online: 17 янв. 2019 г.
Опубликована в печати: 15 мар. 2019 г.
Идентификаторы БД:
Web of science: WOS:000458626600007
Scopus: 2-s2.0-85060209485
РИНЦ: 38681348
Chemical Abstracts: 2019:619000
Chemical Abstracts (print): 170:490990
OpenAlex: W2910471099
Цитирование в БД:
БД Цитирований
Scopus 11
Web of science 11
РИНЦ 9
OpenAlex 11
Альметрики: