Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2=CF) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2=CF) Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039

Output data

Year: 2002, Volume: 43, Number: 45, Pages: 8111-8114 Pages count : 4 DOI: 10.1016/s0040-4039(02)01922-6

Tags

perfluorophenyltrifluoroborate salt; perfluoroethenyltrifluoroborate salt; cross-coupling; palladium; silveroxide

Authors

Frohn H.-J. ¹ , Adonin N.Yu. ² , Bardin V.V. ² , Starichenko V.F. ²

Affiliations

1	Institute of Chemistry, Inorganic Chemistry, Gerhard-Mercator-University Duisburg, Lotharstraße 1, D-47048 Duisburg, Germany
2	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrentjev Ave. 9, 630090 Novosibirsk, Russia

Potassium pentafluorophenyl- and trifluorovinyltrifluoroborates, both containing electron-poor organo groups, reacted with iodobenzene and p-substituted iodobenzenes in the presence of palladium compounds and stoichiometric amounts of silveroxide to the fluorinated cross-coupling products in very good yields. Substituted bromobenzenes were less efficient substrates.

Frohn H.-J. , Adonin N.Y. , Bardin V.V. , Starichenko V.F.
Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2=CF)
Tetrahedron Letters. 2002. V.43. N45. P.8111-8114. DOI: 10.1016/s0040-4039(02)01922-6 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 16, 2002
Accepted:	Sep 6, 2002
Published online:	Oct 11, 2002
Published print:	Nov 4, 2002

Web of science:	WOS:000178774600026
Scopus:	2-s2.0-0037020637
Elibrary:	13392880
Chemical Abstracts:	2002:788574
Chemical Abstracts (print):	138:221271
OpenAlex:	W1999459646

DB	Citing
Web of science	61
Scopus	68
OpenAlex	72