Cyclic Carbonates Synthesis from Epoxides and CO2 over Metal–Organic Framework Cr-MIL-101 | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cyclic Carbonates Synthesis from Epoxides and CO2 over Metal–Organic Framework Cr-MIL-101 Full article

Journal

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Output data

Year: 2013, Volume: 298, Pages: 179-185 Pages count : 7 DOI: 10.1016/j.jcat.2012.11.029

Tags

Carbon dioxide, Cyclic carbonates, Cycloaddition, Heterogeneous catalysis, Metal-organic framework, MIL-101

Authors

Zalomaeva Olga V. ¹ , Chibiryaev Andrey M. ² , Kovalenko Konstantin A. ³ , Kholdeeva Oxana A. ¹ , Balzhinimaev Bair S. ¹ , Fedin Vladimir P. ³

Affiliations

1	Boreskov Institute of Catalysis, 5, av. Acad. Lavrentiev, Novosibirsk 630090, Russia
2	Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9, av. Acad. Lavrentiev, Novosibirsk 630090, Russia
3	Nikolaev Institute of Inorganic Chemistry, 3, av. Acad. Lavrentiev, Novosibirsk 630090, Russia

Funding (1)

Президиум РАН

5.6.1

The catalytic performance of the metal–organic framework Cr-MIL-101 in solvent-free coupling of CO2 and epoxides to produce cyclic carbonates has been explored at both high-pressure (100 atm CO2) and low-pressure (8 atm CO2) conditions in the temperature range of 25–120 °C. The presence of tetrabutylammonium bromide as co-catalyst was found to be crucial for the formation of the cyclic carbonates at mild reaction conditions (8 atm CO2, 25 °C). The yield of the styrene carbonate attained 95% at 98% substrate conversion after 48 h. Cycloaddition of CO2 to propylene oxide gave propylene carbonate with 82% yield at 91% conversion after 24 h. Heterogeneous nature of catalysis was proved by hot catalyst filtration test, indicating no leaching of active chromium species. However, a deterioration of the catalytic properties occurred after catalyst recycling due to pores blockage with the reaction products and gradual degradation of the MIL-101 structure.

Zalomaeva O.V. , Chibiryaev A.M. , Kovalenko K.A. , Kholdeeva O.A. , Balzhinimaev B.S. , Fedin V.P.
Cyclic Carbonates Synthesis from Epoxides and CO2 over Metal–Organic Framework Cr-MIL-101
Journal of Catalysis. 2013. V.298. P.179-185. DOI: 10.1016/j.jcat.2012.11.029 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 2, 2012
Accepted:	Nov 27, 2012
Published online:	Jan 4, 2013
Published print:	Feb 1, 2013

Web of science:	WOS:000316155700020
Scopus:	2-s2.0-84873369865
Elibrary:	20428475
Chemical Abstracts:	2013:190177
Chemical Abstracts (print):	158:331080
OpenAlex:	W2034142805

DB	Citing
Web of science	274
Scopus	286
Elibrary	263
OpenAlex	270