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Effect of Ionic Liquid BMImBr on Palladium-Catalyzed Oxidation of Ethylene with LiNO3 Full article

Journal Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837
Output data Year: 2009, Volume: 97, Number: 2, Pages: 191-197 Pages count : 7 DOI: 10.1007/s11144-009-0043-z
Tags Bromination, Ionic liquid, Nitrate, Oxidation, Palladium(II)
Authors Balandina Tatiana A. 1 , Larina Tatiana V. 1 , Trebushat Dmitry V. 1 , Adonin Nikolai Yu. 1 , Kuznetsova Nina I. 1
Affiliations
1 Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia

Abstract: Oxidative bromination of ethylene was found to proceed effectively in the presence of a catalytic system Pd(OAc)2–LiNO3 in two-component BMImBr–HOAc and three-component BMImBr–HOAc–H2O solvents. At a large content of BMImBr, conversion of ethylene was found to yield 1,2-dibromoethane with a selectivity over 95%. The composition of the Pd(OAc)2–LiNO3 solutions was followed during the reaction of ethylene by means of UV–Vis spectroscopy.
Cite: Balandina T.A. , Larina T.V. , Trebushat D.V. , Adonin N.Y. , Kuznetsova N.I.
Effect of Ionic Liquid BMImBr on Palladium-Catalyzed Oxidation of Ethylene with LiNO3
Reaction Kinetics and Catalysis Letters. 2009. V.97. N2. P.191-197. DOI: 10.1007/s11144-009-0043-z WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Dec 25, 2008
Accepted: May 5, 2009
Published online: Jul 14, 2009
Published print: Aug 1, 2009
Identifiers:
Web of science: WOS:000268445800004
Scopus: 2-s2.0-68249096308
Elibrary: 13600256
Chemical Abstracts: 2009:915315
Chemical Abstracts (print): 152:147596
OpenAlex: W2029493225
Citing:
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Web of science 3
Scopus 3
Elibrary 3
OpenAlex 3
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