Catalytic Oxidation of Fatty Acids. II. Epoxidation and Oxidative Cleavage of Unsaturated Fatty Acid Esters Containing Additional Functional Groups Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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| Output data | Year: 2009, Volume: 98, Number: 1, Pages: 9-17 Pages count : 9 DOI: 10.1007/s11144-009-0054-9 | ||||
| Tags | Methyl esters of unsaturated fatty acids, Oxidation, Peroxopolyoxotungstates, Phase-transfer catalysis, Quaternary ammonium cations | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Президиум РАН | 5.7.3 |
| 2 | Russian Foundation for Basic Research |
Abstract:
Methyl esters of monounsaturated fatty acids were oxidized with aqueous hydrogen peroxide in biphasic organic-aqueous systems in the presence of catalyst [Me(n-C8H17)3N]3{PO4[WO(O2)2]4}. Epoxidation and oxidative cleavage of the C=C bond were found to proceed with high conversion and selectivity in the absence of organic solvents and under rather mild conditions (T < 100 °C, 1 atm).
Cite:
Khlebnikova T.B.
, Pai Z.P.
, Fedoseeva L.A.
, Mattsat Y.V.
Catalytic Oxidation of Fatty Acids. II. Epoxidation and Oxidative Cleavage of Unsaturated Fatty Acid Esters Containing Additional Functional Groups
Reaction Kinetics and Catalysis Letters. 2009. V.98. N1. P.9-17. DOI: 10.1007/s11144-009-0054-9 WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Oxidation of Fatty Acids. II. Epoxidation and Oxidative Cleavage of Unsaturated Fatty Acid Esters Containing Additional Functional Groups
Reaction Kinetics and Catalysis Letters. 2009. V.98. N1. P.9-17. DOI: 10.1007/s11144-009-0054-9 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Oct 13, 2008 |
| Accepted: | Jun 29, 2009 |
| Published online: | Sep 3, 2009 |
| Published print: | Oct 1, 2009 |
Identifiers:
| Web of science: | WOS:000270190100002 |
| Scopus: | 2-s2.0-70349497456 |
| Elibrary: | 22187530 |
| Chemical Abstracts: | 2009:1184509 |
| Chemical Abstracts (print): | 152:381044 |
| OpenAlex: | W2078793035 |