Catalytic Properties of the Macromolecular Polyoxomolybdate Cluster in Selective Oxidation of Sulfides | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Properties of the Macromolecular Polyoxomolybdate Cluster in Selective Oxidation of Sulfides Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2009, Volume: 58, Number: 1, Pages: 134-137 Pages count : 4 DOI: 10.1007/s11172-009-0020-8

Tags

Catalysis, Hydrogen peroxide, Liquid-phase oxidation, Organic sulfides, Polyoxomolybdates, Tert-butyl hydroperoxide

Authors

Izarova N.V. ¹ , Kholdeeva O.A. ² , Sokolov M.N. ^1,3 , Fedin V.P. ^1,3

Affiliations

1	A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentґeva, 630090 Novosibirsk, Russian Federation
2	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentґeva, 630090 Novosibirsk, Russian Federation
3	Novosibirsk State University, 2 ul. Pirogova, 630090 Novosibirsk, Russian Federation

Funding (1)

Russian Foundation for Basic Research

06-03-32831

The catalytic properties of the iron-containing Keplerate [H4Mo72Fe30O254(CH3COO)10-Mo2O7(H2O)H2Mo2O8(H2O)3(H2O)87] • (~80)H2O (1) in the selective liquid-phase oxidation of thio ethers were studied. Compound 1 shows high catalytic activity and selectivity in the oxidation of organic sulfides to sulfoxides when hydrogen peroxide and tert-butyl hydroperoxide are used as oxidants.

Izarova N.V. , Kholdeeva O.A. , Sokolov M.N. , Fedin V.P.
Catalytic Properties of the Macromolecular Polyoxomolybdate Cluster in Selective Oxidation of Sulfides
Russian Chemical Bulletin. 2009. V.58. N1. P.134-137. DOI: 10.1007/s11172-009-0020-8 WOS Scopus РИНЦ ANCAN OpenAlex

Изарова Н.В. , Холдеева О.А. , Соколов М.Н. , Федин В.П.
Исследование каталитических свойств макромолекулярного полиоксомолибдата в реакциях селективного окисления тиоэфиров
Известия Академии наук. Серия химическая. 2009. №1. С.134-137. РИНЦ

Submitted:	Jan 30, 2008
Published print:	Jan 1, 2009
Published online:	Mar 2, 2010

Web of science:	WOS:000276107500020
Scopus:	2-s2.0-77649263302
Elibrary:	15306279
Chemical Abstracts:	2010:257465
Chemical Abstracts (print):	153:358479
OpenAlex:	W2078437281

DB	Citing
Web of science	35
Scopus	35
Elibrary	36
OpenAlex	36