Complexes of Copper(II) and Cobalt(II) Halides with 4-(3,5-Dimethyl-1H- Pyrazol-1-yl)-6-Methyl-2-Phenylpyrimidine: Synthesis, Structures, and Properties | Sciact - CRIS-system of Boreskov Institute of Catalysis

Complexes of Copper(II) and Cobalt(II) Halides with 4-(3,5-Dimethyl-1H- Pyrazol-1-yl)-6-Methyl-2-Phenylpyrimidine: Synthesis, Structures, and Properties Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2009, Volume: 35, Number: 8, Pages: 597-608 Pages count : 12 DOI: 10.1134/S1070328409080077

Tags

Pyrazole; Coordination Chemistry; Coordination Polyhedron; Pyrimidine Ring; Ethene Polymerization

Authors

Bushuev M.B. ^1,2 , Krivopalov V.P. ³ , Peresypkina E.V. ¹ , Virovets A.V. ¹ , Shvedenkov Yu.G. ¹ , Sheludyakova L.A. ¹ , Semikolenova N.V. ⁴ , Zakharov V.A. ⁴ , Larionov S.V. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
4	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

Copper(II) and cobalt(II) complexes with 4-(3,5-dimethyl-1H-pyrazol-1-yl)-6-methyl-2-phenylpyrimidine (L) of the general formula MLX2 (M = Cu(II), X = Cl and Br; M = Co(II), X = Cl, Br, and I) were obtained. According to X-ray diffraction data, CuLBr2 and CoLX2 (X = Cl, Br, and I) are mononuclear molecular complexes. The ligand L is coordinated to the metal atom in a chelating bidentate fashion through the N atoms of the pyrimidine and pyrazole rings. The coordination polyhedron of the metal atom is extended to a distorted tetrahedron by two halide ions. In solution, CuLBr2 undergoes slow transformation into CuL(1−x)L′ x Br2 and the binuclear (X-ray diffraction data) Cu(I) complex [CuL(1−x)L′ x Br]2 (L′ is 4-(4-bromo-3,5-dimethyl-1H-pyrazol-1-yl)-6-methyl-2-phenylpyrimidine). The complexes MLX2 show weak antiferromagnetic interactions between the M2+ ions.

Bushuev M.B. , Krivopalov V.P. , Peresypkina E.V. , Virovets A.V. , Shvedenkov Y.G. , Sheludyakova L.A. , Semikolenova N.V. , Zakharov V.A. , Larionov S.V.
Complexes of Copper(II) and Cobalt(II) Halides with 4-(3,5-Dimethyl-1H- Pyrazol-1-yl)-6-Methyl-2-Phenylpyrimidine: Synthesis, Structures, and Properties
Russian Journal of Coordination Chemistry. 2009. V.35. N8. P.597-608. DOI: 10.1134/S1070328409080077 WOS Scopus РИНЦ ANCAN OpenAlex

Бушуев М.Б. , Кривопалов В.П. , Пересыпкина Е.В. , Вировец А.В. , Шведенков Ю.Г. , Шелудякова Л.А. , Семиколенова Н.В. , Захаров В.А. , Ларионов С.В.
Синтез, строение и свойства координационных соединений галогенидов меди(II) и кобальта(II) C 4-(3,5-диметил-1н-пиразол-1-ил)-6-метил-2-фенилпиримидином
Координационная химия. 2009. Т.35. №8. С.606-617. РИНЦ

Submitted:	Dec 16, 2008
Published print:	Aug 1, 2009
Published online:	Aug 21, 2009

Web of science:	WOS:000269210500007
Scopus:	2-s2.0-69249165986
Elibrary:	15298837
Chemical Abstracts:	2009:1019581
Chemical Abstracts (print):	152:444842
OpenAlex:	W2088078237

DB	Citing
Web of science	7
Scopus	7
Elibrary	7
OpenAlex	7