Synthesis of New Chiral Schiff Bases from (+)-3-Carene and Their Use in Asymmetric Oxidation of Sulfides Catalyzed by Metal Complexes Full article
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Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393 |
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| Output data | Year: 2009, Volume: 45, Number: 6, Pages: 815-824 Pages count : 10 DOI: 10.1134/S1070428009060037 | ||||
| Tags | Schiff Base; Acac; Optical Purity; Anhydrous Methanol; Compound XIIa | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Foundation for Basic Research | 06-03-32052 |
Abstract:
A number of new chiral Schiff bases were synthesized starting from accessible monoterpene (+)-3-carene, and the products were used as ligands in metal complex-catalyzed oxidation of sulfides to chiral sulfoxides. The optical purity and the sign of optical rotation of chiral sulfoxides were found to strongly depend on the oxidation temperature.
Cite:
Koneva E.A.
, Volcho K.P.
, Korchagina D.V.
, Salakhutdinov N.F.
, Tolstikov A.G.
Synthesis of New Chiral Schiff Bases from (+)-3-Carene and Their Use in Asymmetric Oxidation of Sulfides Catalyzed by Metal Complexes
Russian Journal of Organic Chemistry. 2009. V.45. N6. P.815-824. DOI: 10.1134/S1070428009060037 WOS Scopus РИНЦ ANCAN OpenAlex
Synthesis of New Chiral Schiff Bases from (+)-3-Carene and Their Use in Asymmetric Oxidation of Sulfides Catalyzed by Metal Complexes
Russian Journal of Organic Chemistry. 2009. V.45. N6. P.815-824. DOI: 10.1134/S1070428009060037 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Конева Е.А.
, Волчо К.П.
, Корчагина Д.В.
, Салахутдинов Н.Ф.
, Толстиков А.Г.
Синтез новых хиральных оснований Шиффа на основе (+) 3карена и использование их в асимметрическом металлокомплексном окислении сульфидов
Журнал органической химии. 2009. Т.45. №6. С.832-841. РИНЦ
Синтез новых хиральных оснований Шиффа на основе (+) 3карена и использование их в асимметрическом металлокомплексном окислении сульфидов
Журнал органической химии. 2009. Т.45. №6. С.832-841. РИНЦ
Dates:
| Submitted: | Jul 28, 2008 |
| Published print: | Jun 1, 2009 |
| Published online: | Jul 11, 2009 |
Identifiers:
| Web of science: | WOS:000267898400003 |
| Scopus: | 2-s2.0-70350054764 |
| Elibrary: | 15300224 |
| Chemical Abstracts: | 2009:845135 |
| Chemical Abstracts (print): | 152:37145 |
| OpenAlex: | W2061598712 |