Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2018, Volume: 59, Number: 6, Pages: 727-734 Pages count : 8 DOI: 10.1134/s0023158418060101 | ||||
| Tags | photocatalysis hydrogen production Cd1–xZnxS simulations Langmuir–Hinshelwood equation | ||||
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0016 |
Abstract:
The dependences of the rate of the photocatalytic hydrogen production in ethanol aqueous solutions on the concentration of ethanol and sodium hydroxide on the 1% Pt/10% Ni(OH)2/Cd0.3Zn0.7S photocatalyst under visible light irradiation (λ = 450 nm) are studied. To describe kinetic data, the Langmuir–Hinshelwood equation was modified. An equation was proposed that reflects the dependence of the reaction rate on the concentration of NaOH, and an equation was derived for the first time that shows the dependence of the rate of photocatalytic hydrogen production from the concentrations of both reactants, ethanol and sodium hydroxide. The validity of the proposed equations was confirmed by their use for the description of the experimental data obtained in this work and reported earlier.
Cite:
Markovskaya D.V.
, Kozlova E.A.
Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide
Kinetics and Catalysis. 2018. V.59. N6. P.727-734. DOI: 10.1134/s0023158418060101 WOS Scopus РИНЦ AN OpenAlex
Formal Kinetic Description of Photocatalytic Hydrogen Evolution from Ethanol Aqueous Solutions in the Presence of Sodium Hydroxide
Kinetics and Catalysis. 2018. V.59. N6. P.727-734. DOI: 10.1134/s0023158418060101 WOS Scopus РИНЦ AN OpenAlex
Original:
Марковская Д.В.
, Козлова Е.А.
Формально-кинетическое описание закономерностей фотокаталитического выделения водорода из водных растворов этанола в присутствии гидроксида натрия
Кинетика и катализ. 2018. Т.59. №6. С.685-693. DOI: 10.1134/S0453881118060138 РИНЦ OpenAlex
Формально-кинетическое описание закономерностей фотокаталитического выделения водорода из водных растворов этанола в присутствии гидроксида натрия
Кинетика и катализ. 2018. Т.59. №6. С.685-693. DOI: 10.1134/S0453881118060138 РИНЦ OpenAlex
Dates:
| Submitted: | Apr 3, 2018 |
| Published print: | Nov 1, 2018 |
| Published online: | Mar 4, 2019 |
Identifiers:
| Web of science: | WOS:000460765200005 |
| Scopus: | 2-s2.0-85062590803 |
| Elibrary: | 38679869 |
| Chemical Abstracts: | 2019:795077 |
| OpenAlex: | W2918860406 |