In situ XRD Investigation of Co3O4 Reduction Full article
| Conference |
11th European Powder Diffraction Conference 19-22 Sep 2008 , Warsaw |
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| Journal |
Zeitschrift fur Kristallographie Supplement
ISSN: 0930-486X |
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| Output data | Year: 2009, Pages: 329-334 Pages count : 6 DOI: 10.1524/zksu.2009.0048 | ||||
| Tags | Alumina, Cobalt oxide, Fischer-Tropsch catalysts, In situ XRD, Reduction, Staking faults | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 08-03-00964 |
| 2 | Siberian Branch of the Russian Academy of Sciences | 17 |
Abstract:
In situ X-ray diffraction (XRD) method was used to investigate the Co3O4 reduction in catalyst supported on γ-Al2O3 and oxide monophase sample. Initial structure of Co3O4 in both samples is similar and contains vacancies in the cation positions. In spite of this reduction process of Co3O4 is different for supported and monophase samples as has been shown by in situ XRD. In monophase sample the cobalt oxide is reduced to metallic cobalt (hcp) directly. On the contrary the two-stage reduction is observed for supported sample: Co3O4 is reduced to CoO and then to metallic Co (fcc). In both cases nanoparticles of metallic cobalt contains high concentration of stacking faults.
Cite:
Bulavchenko O.A.
, Cherepanova S.V.
, Tsybulya S.V.
In situ XRD Investigation of Co3O4 Reduction
Zeitschrift fur Kristallographie Supplement. 2009. P.329-334. DOI: 10.1524/zksu.2009.0048 WOS Scopus РИНЦ OpenAlex
In situ XRD Investigation of Co3O4 Reduction
Zeitschrift fur Kristallographie Supplement. 2009. P.329-334. DOI: 10.1524/zksu.2009.0048 WOS Scopus РИНЦ OpenAlex
Dates:
| Published print: | Sep 1, 2009 |
Identifiers:
| Web of science: | WOS:000271325700017 |
| Scopus: | 2-s2.0-84863006931 |
| Elibrary: | 20546734 |
| OpenAlex: | W2023535570 |