Ni–Cu and Ni–Co Alloys: Synthesis, Structure, and Catalytic Activity for the Decomposition of Chlorinated Hydrocarbons | Sciact - CRIS-system of Boreskov Institute of Catalysis

Ni–Cu and Ni–Co Alloys: Synthesis, Structure, and Catalytic Activity for the Decomposition of Chlorinated Hydrocarbons Full article

Journal

Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172

Output data

Year: 2014, Volume: 50, Number: 6, Pages: 566-571 Pages count : 6 DOI: 10.1134/S0020168514060156

Tags

Induction Period; Metal Nitrate; Chlorinate Hydrocarbon; Single Phase Alloy; Iron Group Metal

Authors

Rudnev A.V. ¹ , Lysakova A.S. ² , Plyusnin P.E. ^1,3 , Bauman Yu.I. ⁴ , Shubin Yu.V. ^1,3 , Mishakov I.V. ^2,4 , Vedyagin A.A. ^2,4 , Buyanov R.A. ⁴

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
2	Novosibirsk State Technical University, pr. Marksa 20, Novosibirsk, 630073 Russia
3	Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090 Russia
4	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia

Funding (3)

1	Russian Foundation for Basic Research	14-03-00411
2	Президиум РАН	5.2.2
3	Council for Grants of the President of the Russian Federation	МК-1934.2013.3

Homogeneous NixCu1 – x and NixCo1 – x (x = 0.90–0.99) alloys have been prepared through the coprecipitation of precursors (hydroxides or carbonates) and reduction of the precipitate. The formation of singlephase NixM1 – x alloys in all of the samples has been confirmed by Xray diffraction. We have assessed the catalytic activity of the alloys for 1,2dichloroethane decomposition with carbon nanomaterial (CNM) formation. The highest catalytic activity (CNM yield, 26–27 g/gcat) was offered by the nickel alloys containing ~1 at % Cu or Co. The carbon material obtained has the form of segmented submicron wires with high morphological uniformity.

Rudnev A.V. , Lysakova A.S. , Plyusnin P.E. , Bauman Y.I. , Shubin Y.V. , Mishakov I.V. , Vedyagin A.A. , Buyanov R.A.
Ni–Cu and Ni–Co Alloys: Synthesis, Structure, and Catalytic Activity for the Decomposition of Chlorinated Hydrocarbons
Inorganic Materials. 2014. V.50. N6. P.566-571. DOI: 10.1134/S0020168514060156 WOS Scopus РИНЦ ANCAN OpenAlex

Руднев А.В. , Лысакова А.С. , Плюснин П.Е. , Бауман Ю.И. , Шубин Ю.В. , Мишаков И.В. , Ведягин А.А. , Буянов Р.А.
Синтез, структура и каталитическая активность при разложении хлоруглеводородов сплавов никеля с медью или кобальтом
Неорганические материалы. 2014. Т.50. №6. С.613-619. DOI: 10.7868/S0002337X14060153 РИНЦ OpenAlex

Submitted:	Sep 23, 2013
Accepted:	Dec 16, 2013
Published online:	May 6, 2014
Published print:	Jun 1, 2014

Web of science:	WOS:000335664100005
Scopus:	2-s2.0-84902511406
Elibrary:	24059618
Chemical Abstracts:	2014:737869
Chemical Abstracts (print):	161:672442
OpenAlex:	W2031931539

DB	Citing
Web of science	21
Scopus	22
Elibrary	22
OpenAlex	21