Effect of Method of Boron Introduction into NiMo/Al2O3 Protective-Layer Catalysts on the Removal of Silicon from Diesel Fractions Научная публикация
Журнал |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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Вых. Данные | Год: 2018, Том: 91, Номер: 12, Страницы: 2022−2029 Страниц : 8 DOI: 10.1134/S1070427218120145 | ||
Ключевые слова | protective-layer catalysts, removal of silicon, diesel fraction, hydrodesulfurization | ||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Министерство образования и науки Российской Федерации | 14.604.21.0155 (RFMEFI60417X0155) |
Реферат:
NiMo/γ-Al2O3 protective-layer catalysts for removing silicon from diesel fractions were examined. The catalysts differ in the way in which boron is introduced into the support. The supports and catalysts were examined by X-ray diffraction analysis, transmission electron microscopy, IR spectroscopy, and adsorption–desorption of nitrogen. The catalysts were tested in hydropurification of the diesel fraction to which decamethylcyclopentanesiloxane was added as a model silicon compound. It was shown that introduction of boron into the support results in that the surface area of the supports and catalysts increases. If boron is introduced into pseudoboehmite, massive particles of the Ni–Mo–S phase are formed. It was found that the highest capacity for silicon is observed for the catalyst into which boron is introduced in the stage of pseudoboehmite preparation.
Библиографическая ссылка:
Koval’skaya A.A.
, Nadeina K.A.
, Kazakov M.O.
, Danilevich V.V.
, Danilova I.G.
, Gerasimov E.Y.
, Klimov O.V.
, Noskov A.S.
Effect of Method of Boron Introduction into NiMo/Al2O3 Protective-Layer Catalysts on the Removal of Silicon from Diesel Fractions
Russian Journal of Applied Chemistry. 2018. V.91. N12. P.2022−2029. DOI: 10.1134/S1070427218120145 WOS Scopus РИНЦ CAPlusCA OpenAlex
Effect of Method of Boron Introduction into NiMo/Al2O3 Protective-Layer Catalysts on the Removal of Silicon from Diesel Fractions
Russian Journal of Applied Chemistry. 2018. V.91. N12. P.2022−2029. DOI: 10.1134/S1070427218120145 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная:
Ковальская А.А.
, Надеина К.А.
, Казаков М.О.
, Данилевич В.В.
, Данилова И.Г.
, Герасимов Е.Ю.
, Климов О.В.
, Носков А.С.
Влияние способа введения бора в NiMo/Al2O3 катализаторы защитного слоя на удаление кремния из дизельных фракций
Журнал прикладной химии. 2018. Т.91. №12. С.1760-1767. DOI: 10.1134/S0044461818120101 РИНЦ
Влияние способа введения бора в NiMo/Al2O3 катализаторы защитного слоя на удаление кремния из дизельных фракций
Журнал прикладной химии. 2018. Т.91. №12. С.1760-1767. DOI: 10.1134/S0044461818120101 РИНЦ
Даты:
Поступила в редакцию: | 21 окт. 2018 г. |
Опубликована в печати: | 1 дек. 2018 г. |
Опубликована online: | 5 мар. 2019 г. |
Идентификаторы БД:
Web of science: | WOS:000460478800014 |
Scopus: | 2-s2.0-85062599373 |
РИНЦ: | 38685301 |
Chemical Abstracts: | 2019:798385 |
Chemical Abstracts (print): | 170:562580 |
OpenAlex: | W2918546202 |