Thermochemical Energy Storage by LiNO3-Doped Mg(OH)2: Rehydration Study | Sciact - CRIS-система Института катализа

Thermochemical Energy Storage by LiNO3-Doped Mg(OH)2: Rehydration Study Научная публикация

Журнал

Journal of Energy Storage
ISSN: 2352-152X

Вых. Данные

Год: 2019, Том: 22, Страницы: 302-310 Страниц : 9 DOI: 10.1016/j.est.2019.01.014

Ключевые слова

Thermochemical energy storage; Rehydration kinetics; Magnesium oxide; Magnesium hydroxide; Salt additive; Cyclic stability

Авторы

Shkatulov Alexandr ^1,2 , Takasu Hiroki ³ , Kato Yukitaka ⁴ , Aristov Yuri ^1,4

Организации

1	Boreskov Institute of Catalysis, Ac. Lavrentieva Av. 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Pirogova Str. 2, Novosibirsk, 630090, Russia
3	Graduate Major in Nuclear Engineering, Tokyo Institute of Technology, 2-12-1-N1-22, Ookayama, Meguro-ku, Tokyo 152-8550, Japan
4	Laboratory for Advanced Nuclear Energy, Institute of Innovative Research, Tokyo Institute of Technology, 2-12-1-N1-22, Ookayama, Meguro-ku, Tokyo 152-8550, Japan

Информация о финансировании (1)

Tōkyō Kōgyō Daigaku; Tokodai

Tokyo Tech World Research Hub Initiative (WRHI) Program

Thermochemical energy storage (TCES) is an emerging technology promising for reuse of industrial waste heat and harvesting solar energy. Recently, a novel material, namely, a magnesium hydroxide doped with lithium nitrate LiNO3/Mg(OH)2, was suggested for TCES at temperature lower than 300 °C [1]. The LiNO3 additive to Mg(OH)2 was found to decrease the Mg(OH)2 dehydration temperature by 76 °C which, to the best of our knowledge, is the largest depression reported in the literature so far. The large heat storage capacity (1250 J/g) and fast dehydration made this material promising for TCES. In this work, the LiNO3/Mg(OH)2 is studied with a focus on the reverse reaction of its hydration by water vapour which allows the stored heat to be released. The rehydration kinetics is studied at various temperatures (90–150 °C), water vapour pressures (16.7–33.5 kPa), and LiNO3 contents (0.5–20 wt.%) to outline the boundary conditions of closed TCES cycle for which this material may be used. The material is found to be stable in ten successive de-/rehydration cycles. Finally, the applicability of the material for storage of heat from some particular heat sources is discussed.

Shkatulov A. , Takasu H. , Kato Y. , Aristov Y.
Thermochemical Energy Storage by LiNO3-Doped Mg(OH)2: Rehydration Study
Journal of Energy Storage. 2019. V.22. P.302-310. DOI: 10.1016/j.est.2019.01.014 WOS Scopus РИНЦ OpenAlex

Поступила в редакцию:	1 окт. 2018 г.
Принята к публикации:	15 янв. 2019 г.
Опубликована online:	1 мар. 2019 г.
Опубликована в печати:	1 апр. 2019 г.

Web of science:	WOS:000462506300032
Scopus:	2-s2.0-85062233673
РИНЦ:	38694627
OpenAlex:	W2920269042

БД	Цитирований
Scopus	22
Web of science	22
РИНЦ	18
OpenAlex	19