Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia Full article

Journal

Catalysis for Sustainable Energy
ISSN: 2084-6819

Output data

Year: 2018, Volume: 5, Number: 1, Pages: 49-58 Pages count : 10 DOI: 10.1515/cse-2018-0007

Tags

one-pot alcohol amination, gold, mixed oxides, ceriaalumina, ceria-alumina-zirconia, alumina, terpene alcohol

Authors

Demidova Yu.S. ^1,2 , Simakova I.L. ² , Suslov E.V. ³ , Volcho K.P. ^2,3 , Salakhutdinov N.F. ^2,3 , Simakov A. ⁴ , Murzin D.Yu. ⁵

Affiliations

1	Boreskov Institute of Catalysis, pr. Lavrentieva, 5, 630090, Novosibirsk, Russia
2	Novosibirsk State University, Pirogova 2, 630090, Novosibirsk, Russia
3	Novosibirsk Institute of Organic Chemistry, pr. Lavrentieva, 9, 630090, Novosibirsk, Russia
4	Universidad Nacional Autónoma de México, Centro de Nanociencias y Nanotecnología, km. 107 carretera Tijuana a Ensenada, C.P. 22860, Ensenada, Baja California, México
5	Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Biskopsgatan 8, FI-20500, Turku/Åbo, Finland

Funding (2)

1	Russian Foundation for Basic Research	16-33-60028
2	National Autonomous University of Mexico	117203

In the current work gold catalysts supported on both commercial oxides and oxides synthesized by the sol-gel method were used for the one-pot alcohol amination of myrtenol. In general, utilization of metal oxides synthesized by the sol-gel method as the gold catalyst support enhanced the knowledge regarding key parameters determining catalytic behavior. Synthesized alumina was characterized by stronger acid sites favoring primary amine accumulation on the catalyst surface, as compared to the commercial oxide. Utilization of mixed metal oxides synthesized by the sol-gel method resulted in the non-additive behavior of different oxides enhancing the catalytic activity. Introduction of ceria into alumina modified the support basicity resulting in more efficient alcohol activation.

Demidova Y.S. , Simakova I.L. , Suslov E.V. , Volcho K.P. , Salakhutdinov N.F. , Simakov A. , Murzin D.Y.
Catalytic Myrtenol Amination over Gold, Supported on Alumina Doped with Ceria and Zirconia

Catalysis for Sustainable Energy. 2018. V.5. N1. P.49-58. DOI: 10.1515/cse-2018-0007 РИНЦ AN OpenAlex

Full text from publisher

Submitted:	Oct 29, 2018
Accepted:	Nov 8, 2018
Published print:	Dec 1, 2018
Published online:	Dec 31, 2018

Elibrary:	44642882
Chemical Abstracts:	2019:2274459
OpenAlex:	W2917806931

DB	Citing
Elibrary	1
OpenAlex	2