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Formic Acid Production Via Methane Peroxide Oxidation Over Oxalic Acid Activated Fe-MFI Catalysts Научная публикация

Конференция 4th International Symposium on the Catalysis for Clean Energy and Sustainable Chemistry
09-11 июл. 2018 , Bilbao
Журнал Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Вых. Данные Год: 2019, Том: 62, Номер: 5-6, Страницы: 491-507 Страниц : 17 DOI: 10.1007/s11244-019-01151-8
Ключевые слова Methane; Formic acid; Methanol; Peroxide oxidation; Fe-ZSM-5; Oxalic acid
Авторы Taran Oxana P. 1,2,3 , Yashnik Svetlana A. 1 , Boltenkov Vadim V. 1 , Parkhomchuk Ekaterina V. 1 , Sashkina Kseniya A. 1 , Ayusheev Artemiy B. 1 , Babushkin Dmitrii E. 1 , Parmon Valentin N. 1
Организации
1 Boreskov Institute of Catalysis SB RAS, Akad. Lavrentiev Av., 5, Novosibirsk, Russia 630090
2 Institute of Chemistry and Chemical Technology SB RAS, FRC KSC SB RAS, Akademgorodok St., 50/24, Krasnoyarsk, Russia 660036
3 Siberian Federal University, Svobodny Av., 79, Krasnoyarsk, Russia 660041

Информация о финансировании (1)

1 Российский научный фонд 17-73-30032

Реферат: The process of synthesis of formic acid via partial peroxide oxidation of methane over Fe-MFI zeolites, as well as the influence of the catalyst activation by oxalic acid on the process parameters (conversion and selectivity) was studied. XRD, ICP-OES, SEM, UV–Vis DR, ESR, NH3-TPD, 27Al MAS NMR, N2 adsorption techniques were used for the catalyst characterization. The observed increase in TOF, selectivity to formic acid and efficiency of H2O2 utilization upon the catalyst activation with oxalic acid was accounted for by the formation of oligomeric oxo-clusters of Fe-ions and by an increase in the total acidity of the catalysts. The process of oxidation of main intermediates of the reaction, such as methanol and formic acid, was studied in the presence and in the absence of methane that allowed the mechanism of methane oxidation to formic acid to be suggested.
Библиографическая ссылка: Taran O.P. , Yashnik S.A. , Boltenkov V.V. , Parkhomchuk E.V. , Sashkina K.A. , Ayusheev A.B. , Babushkin D.E. , Parmon V.N.
Formic Acid Production Via Methane Peroxide Oxidation Over Oxalic Acid Activated Fe-MFI Catalysts
Topics in Catalysis. 2019. V.62. N5-6. P.491-507. DOI: 10.1007/s11244-019-01151-8 WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы: Полный текст от издателя
Даты:
Опубликована online: 4 мар. 2019 г.
Опубликована в печати: 1 июн. 2019 г.
Идентификаторы БД:
Web of science: WOS:000473213000007
Scopus: 2-s2.0-85062671577
РИНЦ: 38579417
Chemical Abstracts: 2019:671650
Chemical Abstracts (print): 171:97190
OpenAlex: W2918294215
Цитирование в БД:
БД Цитирований
Scopus 9
Web of science 9
РИНЦ 9
OpenAlex 12
Альметрики: