Methane Activation by Zn-Modified Zeolites: Solid-State NMR and DRIFTS Investigation of the Performance of Zn2+ and ZnO Sites Тезисы доклада
| Конференция |
The 8th Tokyo Conference on Advanced Catalytic Science and Technology 05-10 авг. 2018 , Токио |
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| Сборник | The 8th Tokyo Conference on Advanced Catalytic Science and Technology Сборник, 2018. |
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| Вых. Данные | Год: 2018, Номер статьи : P1231, Страниц : 2 | ||||||
| Ключевые слова | methane activation, Zn-modified zeolites, solid-state NMR, DRIFTS. | ||||||
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Реферат:
This work addresses an important problem of methane conversion at Zn-modified zeolites. The
mechanism of methane activation has been meticulously investigated with two advanced methods: solid-state
NMR and DRIFTS. Particularly, two different types of possible Zn-sites, isolated Zn2+ cations and small
ZnO clusters located inside of zeolite channels, have been compared with respect to their ability to activate
and convert methane. The kinetics of both H/D exchange of methane-d4 with zeolite Brønsted acid sites and
surface Zn-methyl species formation has been monitored with the solid-state NMR approach in situ. DRIFTS
has revealed methane specific interactions with Zn-sites.
Библиографическая ссылка:
Gabrienko A.
, Arzumanov S.
, Freude D.
, Stepanov A.
Methane Activation by Zn-Modified Zeolites: Solid-State NMR and DRIFTS Investigation of the Performance of Zn2+ and ZnO Sites
В сборнике The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
Methane Activation by Zn-Modified Zeolites: Solid-State NMR and DRIFTS Investigation of the Performance of Zn2+ and ZnO Sites
В сборнике The 8th Tokyo Conference on Advanced Catalytic Science and Technology. 2018.
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