Sulfated Alumina and Zirconia in Isobutane/Butene Alkylation and n-Pentane Isomerization: Catalysis, Acidity, and Surface Sulfate Species Научная публикация
| Конференция |
6th World Congress on Catalysis by Acids and Bases 10-14 мая 2009 , Genova |
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| Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Вых. Данные | Год: 2010, Том: 152, Номер: 1-4, Страницы: 17-23 Страниц : 7 DOI: 10.1016/j.cattod.2009.08.013 | ||
| Ключевые слова | Acidity, IR spectroscopy, Isobutane alkylation, Pentane isomerization, Sulfated alumina, Sulfated zirconia, TPD ammonia | ||
| Авторы |
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| Организации |
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Реферат:
The catalytic behavior of sulfated alumina (SA) and zirconia (SZ) was compared for two acid-catalyzed reactions, i.e., isobutane/butene alkylation and isomerization of n-pentane. For the alkylation reaction, the SZ catalyst gave a higher C5+ alkane yield and much lower selectivity for trimethylpentanes (TMPs) at 2 h TOS. However, TMPs selectivity was comparable for both catalysts at 5.5 h TOS. For the isomerization, high n-pentane conversion was obtained on SZ at the reaction temperature of 100 °C when SA had no activity. Surface sulfate species were identified by IR spectroscopy. The acidity of sulfated oxides was compared by IR spectroscopy using pyridine and carbon monoxide as probe molecules and TPD–MS of ammonia. An effort was made to explain the difference between catalytic behavior of two sulfated oxides in terms of acidity, the nature of surface sulfate species and the formation of hydride species.
Библиографическая ссылка:
Smirnova M.Y.
, Toktarev A.V.
, Ayupov A.B.
, Echevsky G.V.
Sulfated Alumina and Zirconia in Isobutane/Butene Alkylation and n-Pentane Isomerization: Catalysis, Acidity, and Surface Sulfate Species
Catalysis Today. 2010. V.152. N1-4. P.17-23. DOI: 10.1016/j.cattod.2009.08.013 WOS Scopus РИНЦ CAPlusCA OpenAlex
Sulfated Alumina and Zirconia in Isobutane/Butene Alkylation and n-Pentane Isomerization: Catalysis, Acidity, and Surface Sulfate Species
Catalysis Today. 2010. V.152. N1-4. P.17-23. DOI: 10.1016/j.cattod.2009.08.013 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована online: | 25 сент. 2009 г. |
| Опубликована в печати: | 1 июл. 2010 г. |
Идентификаторы БД:
| Web of science: | WOS:000279375900004 |
| Scopus: | 2-s2.0-77954313606 |
| РИНЦ: | 15322006 |
| Chemical Abstracts: | 2010:708909 |
| Chemical Abstracts (print): | 153:314425 |
| OpenAlex: | W2011102934 |