Efficient Synthesis of Salts of the Tetrakis(perfluoroorgano)borate Anion, [B(CFCF2)4]- | Sciact - CRIS-system of Boreskov Institute of Catalysis

Efficient Synthesis of Salts of the Tetrakis(perfluoroorgano)borate Anion, [B(CFCF2)4]- Full article

Journal

Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041

Output data

Year: 2004, Volume: 23, Number: 2, Pages: 172-174 Pages count : 3 DOI: 10.1021/om030610i

Tags

Anisotropy; Crystal structure; Crystalline materials; Methanol; Negative ions; Nuclear magnetic resonance; Salts; Synthesis (chemical); X ray analysis

Authors

Adonin Nicolay Yu. ¹ , Bardin Vadim V. ¹ , Flörke Ulrich ² , Frohn Hermann-Josef ³

Affiliations

1	N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrentjev Avenue, 9, 630090 Novosibirsk, Russia
2	Department of Chemistry, University Paderborn, Warburger Strasse 100, D-33098 Paderborn, Germany
3	Institute of Chemistry, Inorganic Chemistry, University Duisburg-Essen, Lotharstrasse 1, D-47048 Duisburg, Germany

The synthesis and the NMR spectra of the tetrakis(trifluorovinyl)borate salts M[B(CFCF2)4] (M = Li, K, Cs, [NR1R23]) as well as the X-ray crystal structure of the tetramethylammonium salt are reported. These salts were prepared by the reaction of boron trichloride with bis(trifluorovinyl)di-n-butyltin in the presence of tri- and tetraalkylammonium or alkali-metal chlorides in dichloromethane.

Adonin N.Y. , Bardin V.V. , Flörke U. , Frohn H-J.
Efficient Synthesis of Salts of the Tetrakis(perfluoroorgano)borate Anion, [B(CFCF2)4]-
Organometallics. 2004. V.23. N2. P.172-174. DOI: 10.1021/om030610i WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Sep 24, 2003
Published online:	Dec 12, 2003
Published print:	Jan 19, 2004

Web of science:	WOS:000188083900006
Scopus:	2-s2.0-0942299071
Elibrary:	13460441
Chemical Abstracts:	2003:968489
Chemical Abstracts (print):	140:163942
OpenAlex:	W2033594516

DB	Citing
Web of science	6
Scopus	7
OpenAlex	6