Polyfluoroorganoboron-Oxygen Compounds. 5 Feasible Routes to Perfluoroalkyltrimethoxyborates M[CnF2n+1B(OMe)3] (n ≥ 3) Научная публикация
| Журнал |
Zeitschrift fur Anorganische und Allgemeine Chemie
ISSN: 0044-2313 , E-ISSN: 1521-3749 |
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| Вых. Данные | Год: 2007, Том: 633, Номер: 4, Страницы: 647-652 Страниц : 6 DOI: 10.1002/zaac.200600357 | ||||
| Ключевые слова | Perfluoroalkylborates; Perfluoroalkylation; Perfluoroalkyl lithium compounds; NMR spectroscopy | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | German Research Foundation | |
| 2 | Verband der Chemischen Industrie |
Реферат:
A well applicable preparative method for lithium perfluoroalkyltrimethoxyborates, Li[CnF2n+1B(OMe)3] (n = 3, 4, 6), was elaborated which is based on the reaction of B(OMe)3 with CnF2n+1Li generated from CnF2n+1H and t‐BuLi. Alternative perfluoroalkylation reactions of B(OMe)3 with perfluoropropyllithium generated from C3F7I and RLi, perfluoropropylmagnesium bromide, or perfluoropropyltrimethylsilane and potassium fluoride gave less satisfactory results for M[C3F7B(OMe)3]. The conversion of M[CnF2n+1B(OMe)3] salts (M = Li, BrMg) into K[CnF2n+1B(OMe)3] salts and basic properties of the new salts are reported.
Библиографическая ссылка:
Adonin N.Y.
, Bardin V.V.
, Frohn H-J.
Polyfluoroorganoboron-Oxygen Compounds. 5 Feasible Routes to Perfluoroalkyltrimethoxyborates M[CnF2n+1B(OMe)3] (n ≥ 3)
Zeitschrift fur Anorganische und Allgemeine Chemie. 2007. V.633. N4. P.647-652. DOI: 10.1002/zaac.200600357 WOS Scopus РИНЦ CAPlusCA OpenAlex
Polyfluoroorganoboron-Oxygen Compounds. 5 Feasible Routes to Perfluoroalkyltrimethoxyborates M[CnF2n+1B(OMe)3] (n ≥ 3)
Zeitschrift fur Anorganische und Allgemeine Chemie. 2007. V.633. N4. P.647-652. DOI: 10.1002/zaac.200600357 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 18 дек. 2006 г. |
| Опубликована online: | 7 мар. 2007 г. |
| Опубликована в печати: | 1 апр. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000245182100025 |
| Scopus: | 2-s2.0-33947578042 |
| РИНЦ: | 13534788 |
| Chemical Abstracts: | 2007:371687 |
| Chemical Abstracts (print): | 148:262649 |
| OpenAlex: | W1965070742 |