Ball Size or Ball Mass – What Matters in Organic Mechanochemical Synthesis? | Sciact - CRIS-система Института катализа

Ball Size or Ball Mass – What Matters in Organic Mechanochemical Synthesis? Научная публикация

Журнал

CrystEngComm
ISSN: 1466-8033

Вых. Данные

Год: 2019, Том: 21, Номер: 13, Страницы: 2174-2179 Страниц : 6 DOI: 10.1039/c8ce02109k

Ключевые слова

COCRYSTALS; PARAMETERS; SURFACE; LIQUID; ENERGY

Авторы

Michalchuk Adam A.L. ^1,2,4 , Tumanov Ivan A. ^1,3 , Boldyreva Elena V. ^1,3

Организации

1	Novosibirsk State University, Pirogova Str. 2, Novosibirsk, 630090, Russian Federation
2	EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Rd., Edinburgh, UK
3	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, pr. Lavrentieva, 5, Novosibirsk 630090, Russian Federation
4	BAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Straße 11, 12489 Berlin, Germany

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	16-33-60086 (АААА-А15-115121840103-1)
2	Министерство науки и высшего образования Российской Федерации (с 15 мая 2018)	ГЗ-2017-2020

Ball mass is an important parameter that is known to have an influence on the outcome of a mechanochemical reaction induced by ball-milling. A standard way of modifying the ball mass is to change the size of the ball made of the same material. In this case, however, a change in mass is accompanied by a simulatneous change in the ball size. It is therefore not possible to disentangle the effects of mass and surface area in these cases. In the present work we report the results of experiments with specially designed and manufactured balls in which (1) milling ball mass is held constant, but their size differs, and (2) the ball mass is altered, with the diameter of the milling ball being held constant. Using the cocrystallisation of theophylline + nicotinamide as a case study it was found that both diameter and ball mass play crucial roles in determining the rate of a mechanochemical reaction. For comparison, we have also used milling balls with the same size (different mass), and others with the same mass (different size) made of different materials, as would be “traditional”. It was found that, despite having the same size, the lightest milling ball (nylon) was the most efficient in initiating the co-crystallisation, presumably due to the sorption of EtOH. Hence, the results of this manuscript also demonstrate how milling ball material can in fact be the most influential parameter, and potentially counterintuitive to classical mechanics.

Michalchuk A.A.L. , Tumanov I.A. , Boldyreva E.V.
Ball Size or Ball Mass – What Matters in Organic Mechanochemical Synthesis?

CrystEngComm. 2019. V.21. N13. P.2174-2179. DOI: 10.1039/c8ce02109k WOS Scopus РИНЦ CAPlusCA OpenAlex

Полный текст от издателя

Поступила в редакцию:	13 дек. 2018 г.
Принята к публикации:	16 янв. 2019 г.
Опубликована online:	16 янв. 2019 г.
Опубликована в печати:	1 апр. 2019 г.

Web of science:	WOS:000463765700018
Scopus:	2-s2.0-85063411995
РИНЦ:	38686475
Chemical Abstracts:	2019:114754
Chemical Abstracts (print):	170:401574
OpenAlex:	W2909336725

БД	Цитирований
Scopus	49
Web of science	47
РИНЦ	45
OpenAlex	47