Purification of Gasoline Exhaust Gases Using Bimetallic Pd–Rh/δ-Al2O3 Catalysts | Sciact - CRIS-система Института катализа

Purification of Gasoline Exhaust Gases Using Bimetallic Pd–Rh/δ-Al2O3 Catalysts Научная публикация

Журнал

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Вых. Данные

Год: 2019, Том: 127, Номер: 1, Страницы: 137–148 Страниц : 12 DOI: 10.1007/s11144-019-01573-1

Ключевые слова

Bimetallic Pd–Rh alloys; Luminescence spectroscopy; Thermal stability; Three-way catalysts; UV–vis spectroscopy

Авторы

Vedyagin Aleksey A. ^1,2 , Stoyanovskii Vladimir O. ¹ , Kenzhin Roman M. ¹ , Slavinskaya Elena M. ¹ , Plyusnin Pavel E. ^3,4 , Shubin Yury V. ^3,4

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russian Federation
2	National Research Tomsk Polytechnic University, Tomsk, Russian Federation 634050
3	Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation 630090
4	National Research Novosibirsk State University, Novosibirsk, Russian Federation 630090

Информация о финансировании (1)

Министерство образования и науки Российской Федерации

14.581.21.0028 (RFMEFI58117X0028)

Efficient neutralization of the exhaust gases from the automobile engines as well as development of the active and stable catalytic systems for pollution control remain actual challenge since the internal combustion engine was discovered. The present work was focused on the study of metal–metal and metal-support interactions taking place in the palladium- and rhodium-containing samples supported on delta-alumina. Catalytic performance of the catalyst was studied in three-way catalysis under both the stoichiometric and reductive conditions. Thermal stability was examined using a prompt thermal aging procedure. The samples were characterized by means of luminescence and UV–vis spectroscopies, since due to low metal loading the most of other characterization techniques was not applicable. All the samples were found to undergo deactivation during the aging procedure. However, in the case of the alloyed samples, the deactivation process is diminished due to a noticeable metal–metal interaction. The strength of this interaction increases along with decrease of palladium loading and reaches its maximum for PdRh32(alloy) system, which shows the best stability at 1000 °C. For the bimetallic system with Pd:Rh ratio of 4:1, an effect of reactivation was observed at 800 °C. After the aging at 800 °C, the sample has showed the improved catalytic activity. Then, being heated up to 1000 °C, the active metal particles were shown to undergo rapid agglomeration.

Vedyagin A.A. , Stoyanovskii V.O. , Kenzhin R.M. , Slavinskaya E.M. , Plyusnin P.E. , Shubin Y.V.
Purification of Gasoline Exhaust Gases Using Bimetallic Pd–Rh/δ-Al2O3 Catalysts
Reaction Kinetics, Mechanisms and Catalysis. 2019. V.127. N1. P.137–148. DOI: 10.1007/s11144-019-01573-1 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	21 дек. 2018 г.
Принята к публикации:	9 апр. 2019 г.
Опубликована online:	11 апр. 2019 г.
Опубликована в печати:	1 июн. 2019 г.

Web of science:	WOS:000468213500011
Scopus:	2-s2.0-85064268929
РИНЦ:	41795253
Chemical Abstracts:	2019:875397
OpenAlex:	W2935966282

БД	Цитирований
Scopus	15
Web of science	13
РИНЦ	13
OpenAlex	14