Identification of Active Oxygen Species over Fe Complexes in Zeolites Full article
| Conference |
Catalysis by Unique Metal lon Structures in Solid Matrices : NATO Advanced Research Workshop 04-07 Jul 2000 , Prague-Pruhonice |
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| Source | NATO Science Series II: Mathematics, Physics and Chemistry: Catalysis by Unique Metal Ion Structures in Solid Matrices: From Science to Application Compilation, Kluwer Academic Publishers. Dordrecht.2001. 332 c. ISBN 9780792368755. |
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| Journal |
NATO Science Series II: Mathematics Physics and Chemistry
ISSN: 1568-2609 |
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| Output data | Year: 2001, Volume: 13, Pages: 149-163 Pages count : 15 DOI: 10.1007/978-94-010-0782-5_10 | ||
| Tags | oxidation; N2O; methane to methanol; benzene to phenol; FeZSM-5; IR spectroscopy | ||
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Abstract:
In the framework of identification problem of active oxygen species involved in the oxidation catalysis a possible role of M=O, O-2(-) and O- species is analyzed. Particular attention is paid to a recently discovered oxygen species O-alpha formed upon N2O decomposition over Fe complexes in zeolites. High reactivity of a-oxygen coupled with the high concentration allow to reliably identify its participation in the oxidation of methane to methanol and benzene to phenol on the FeZSM-5 surface. Different mechanism of alpha -oxygen insertion into CH4 and C6H6 molecules was revealed using adsorption and isotope methods as well as LR spectroscopy.
Cite:
Panov G.I.
, Dubkov K.A.
, Paukshtis Y.A.
Identification of Active Oxygen Species over Fe Complexes in Zeolites
In compilation NATO Science Series II: Mathematics, Physics and Chemistry: Catalysis by Unique Metal Ion Structures in Solid Matrices: From Science to Application. – Kluwer Academic Publishers., 2001. – Т.13. – C.149-163. – ISBN 9780792368755. DOI: 10.1007/978-94-010-0782-5_10 WOS РИНЦ ANCAN OpenAlex
Identification of Active Oxygen Species over Fe Complexes in Zeolites
In compilation NATO Science Series II: Mathematics, Physics and Chemistry: Catalysis by Unique Metal Ion Structures in Solid Matrices: From Science to Application. – Kluwer Academic Publishers., 2001. – Т.13. – C.149-163. – ISBN 9780792368755. DOI: 10.1007/978-94-010-0782-5_10 WOS РИНЦ ANCAN OpenAlex
Identifiers:
| Web of science: | WOS:000169762900010 |
| Elibrary: | 41853222 |
| Chemical Abstracts: | 2001:327776 |
| Chemical Abstracts (print): | 134:316608 |
| OpenAlex: | W183920949 |