Abstract: Sulphided Co–Mo catalysts prepared by supporting (CoL)2[Mo4(C6H5O7)2O11]·xH2O on γ-Al2O3 were studied. Pores with diameters less than 40 Å in the catalysts preliminary dried at 120 °C were observed. The volume of these pores is proportional to the amount of carbon-containing decomposition products of the citrate ligands. No narrow pores in preliminary calcined catalysts were observed, whereas a sulphided active component was uniformly distributed in pores with diameters greater than 50 Å, independent of the active-metal concentration. The morphology of the active component particles depends on the conditions of the heat pretreatment. Catalysts that contain particles with an average of 2.1 ± 0.2 layers in a stack and pores with diameters of 60–120 Å are the most active in the hydrotreatment of diesel fuels.

Cite: Leonova K.A. , Klimov O.V. , Gerasimov E.Y. , Dik P.P. , Pereyma V.Y. , Budukva S.V. , Noskov A.S.
Textural Characteristics of Sulphided Hydrotreatment Catalysts Prepared Using Co–Mo Complex Compounds
Adsorption. 2013. V.19. N2-4. P.723-731. DOI: 10.1007/s10450-013-9500-0 WOS Scopus РИНЦ ANCAN OpenAlex

Dates:

Submitted:	Oct 29, 2012
Accepted:	Feb 4, 2013
Published online:	Feb 13, 2013
Published print:	Apr 1, 2013

Identifiers:

Web of science:	WOS:000317620800057
Scopus:	2-s2.0-84880701879
Elibrary:	20446525
Chemical Abstracts:	2013:570112
Chemical Abstracts (print):	161:421877
OpenAlex:	W2066141730

Citing:

DB	Citing
Web of science	9
Scopus	8
Elibrary	10
OpenAlex	8

Altmetrics: