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The Study of Structural, Textural and Basic Properties of MgAl- and LiAl-LDH Prepared by Mechanochemical Method Обзор

Журнал Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308
Вых. Данные Год: 2020, Том: 357, Страницы: 638-645 Страниц : 8 DOI: 10.1016/j.cattod.2019.04.069
Ключевые слова Basic properties; Mechanochemical method; Mg(Li) Al-layered double hydroxides; Textural properties
Авторы Stepanova L.N. 1 , Belskaya O.B. 1,2 , Vasilevich А.V. 1 , Gulyaeva T.I. 1 , Leont'eva N.N. 1 , Serkova А.N. 3 , Salanov А.N. 3 , Likholobov V.А. 3
Организации
1 Center of New Chemical Technologies BIC, Neftezavodskaya Str., 54, Omsk, 644040, Russian Federation
2 Omsk State Technical University, Mira Ave., 11, Omsk, 644050, Russian Federation
3 Boreskov Institute of Catalysis, Acad. Lavrentieva Ave., 5, Novosibirsk, 630090, Russian Federation

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 18-03-00476 (АААА-А18-118121190005-7)
2 Российский фонд фундаментальных исследований 18-33-00131 (АААА-А18-118121190006-4)

Реферат: Mechanochemical activation was used to prepare Mg(Li)Al-layered double hydroxides (LDH) with molar ratios of cations Mg/Al = 2 and 4 and Li/Al = 0.5. The influence of cationic composition and nature of interlayer anions (CO 3 2− , OH − ) on the structural properties of LDH and the properties of oxide phases formed by LDH calcination was investigated by XRD and SEM. Textural properties (nitrogen adsorption–desorption isotherms at 77.4 K) and acid-base properties (CO 2 double isotherm method, TPD-CO 2 , aldol condensation of furfural with acetone reaction) were studied in detail for mixed oxides. It was shown that mixed oxides based on the LDH that were prepared by mechanochemical route have high specific surface area and porosity. An increase in the Mg/Al ratio, the introduction of Li, and the use of LDH with OH- counterions made it possible not only to increase the total basicity of mixed oxides but also to vary the fraction of basic sites with a different strength. © 2019
Библиографическая ссылка: Stepanova L.N. , Belskaya O.B. , Vasilevich А.V. , Gulyaeva T.I. , Leont'eva N.N. , Serkova А.N. , Salanov А.N. , Likholobov V.А.
The Study of Structural, Textural and Basic Properties of MgAl- and LiAl-LDH Prepared by Mechanochemical Method
Catalysis Today. 2020. V.357. P.638-645. DOI: 10.1016/j.cattod.2019.04.069 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 24 дек. 2018 г.
Принята к публикации: 18 апр. 2019 г.
Опубликована online: 19 апр. 2019 г.
Опубликована в печати: 1 нояб. 2020 г.
Идентификаторы БД:
Web of science: WOS:000579549200066
Scopus: 2-s2.0-85064381940
РИНЦ: 38747522
Chemical Abstracts: 2019:829055
OpenAlex: W2938590483
Цитирование в БД:
БД Цитирований
Scopus 26
РИНЦ 27
Web of science 25
OpenAlex 27
Альметрики: