Synthesis of 1,4-Dimethyl-9,10-Anthraquinone from 1,4-Naphthoquinone and 2,4-Hexadiene in the Presence of Heteropoly Acids Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2019, Volume: 60, Number: 1, Pages: 69-73 Pages count : 5 DOI: 10.1134/s0023158419010087 | ||
| Tags | anthraquinones; diene synthesis; high-vanadium heteropoly acids | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0008 |
Abstract:
The synthesis of 1,4-dimethyl-9,10-anthraquinone (DMAQ) from 1,4-naphthoquinone and 2,4‑hexadiene was studied based on a new one-step method developed by the authors for the synthesis of substituted anthraquinones. A solution of high-vanadium heteropoly acid with the empirical formula H17P3Mo16V10O89 (HPA-10) was used as a bifunctional (acid and oxidation) catalyst. It was found that a reaction with 2,4-hexadiene, unlike other methylbutadienes, does not proceed so smoothly, and it leads to the formation of a mixture of DMAQ, its dihydro derivative, and tarry products. Possible reasons for the results obtained are discussed.
Cite:
Gogin L.L.
, Zhizhina E.G.
, Pai Z.P.
Synthesis of 1,4-Dimethyl-9,10-Anthraquinone from 1,4-Naphthoquinone and 2,4-Hexadiene in the Presence of Heteropoly Acids
Kinetics and Catalysis. 2019. V.60. N1. P.69-73. DOI: 10.1134/s0023158419010087 WOS Scopus РИНЦ ANCAN OpenAlex
Synthesis of 1,4-Dimethyl-9,10-Anthraquinone from 1,4-Naphthoquinone and 2,4-Hexadiene in the Presence of Heteropoly Acids
Kinetics and Catalysis. 2019. V.60. N1. P.69-73. DOI: 10.1134/s0023158419010087 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Гогин Л.Л.
, Жижина Е.Г.
, Пай З.П.
Синтез 1,4-диметил-9,10-антрахинона из 1,4-нафтохинона и 2,4-гексадиена в присутствии гетерополикислот
Кинетика и катализ. 2019. Т.60. №1. С.75-80. DOI: 10.1134/s045388111901009xRSCI РИНЦ OpenAlex
Синтез 1,4-диметил-9,10-антрахинона из 1,4-нафтохинона и 2,4-гексадиена в присутствии гетерополикислот
Кинетика и катализ. 2019. Т.60. №1. С.75-80. DOI: 10.1134/s045388111901009xRSCI РИНЦ OpenAlex
Dates:
| Submitted: | Jun 27, 2018 |
| Accepted: | Aug 13, 2018 |
| Published print: | Jan 1, 2019 |
| Published online: | May 15, 2019 |
Identifiers:
| Web of science: | WOS:000468063400009 |
| Scopus: | 2-s2.0-85066042843 |
| Elibrary: | 41657980 |
| Chemical Abstracts: | 2019:964965 |
| Chemical Abstracts (print): | 171:61573 |
| OpenAlex: | W2946808818 |