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Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review Review

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2019, Volume: 11, Number: 1, Pages: 34-44 Pages count : 11 DOI: 10.1134/S2070050419010057
Tags acid–base catalysis; paracyclophane; synthesis
Authors Gogin L.L. 1 , Yushchenko D.Y. 1 , Konev V.N. 1 , Sergeev E.E. 1 , Zhizhina E.G. 1 , Khlebnikova T.B. 1 , Pai Z.P. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0008

Abstract: Ways of synthesizing dichloro-[2,2]-paracyclophane (dichloroPCP), a valuable monomer for the manufacturing of polymeric coating used in radioelectronics, are described. There are currently no plants for its production in Russia. Analysis of the considered methods of synthesis show the Hofmann elimination of quaternary ammonium salts is the best technique for the industrial production of dichloroPCP. A promising way of conducting the four-stage synthesis of this product in practice is to use such catalytic technologies as catalysis with alkalis and Lewis acids. © 2019, Pleiades Publishing, Ltd.
Cite: Gogin L.L. , Yushchenko D.Y. , Konev V.N. , Sergeev E.E. , Zhizhina E.G. , Khlebnikova T.B. , Pai Z.P.
Ways of Synthesizing Dichloro-[2,2]-Paracyclophane: A Review
Catalysis in Industry. 2019. V.11. N1. P.34-44. DOI: 10.1134/S2070050419010057 WOS Scopus РИНЦ OpenAlex
Original: Гогин Л.Л. , Ющенко Д.Ю. , Конев В.Н. , Сергеев Е.Е. , Жижина Е.Г. , Хлебникова Т.Б. , Пай З.П.
Дихлоро-[2,2]-парациклофан. Способы синтеза
Катализ в промышленности. 2018. Т.18. №5. С.19-30. DOI: 10.18412/1816-0387-2018-5-19-30 РИНЦ AN OpenAlex
Dates:
Submitted: Mar 22, 2018
Published print: Jan 1, 2019
Published online: May 17, 2019
Identifiers:
Web of science: WOS:000468319900003
Scopus: 2-s2.0-85065918483
Elibrary: 39006388
OpenAlex: W2945832263
Citing:
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