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The Oxidative Dehydrogenation of Ethane: Convectional vs Microwave Heating of Catalysts Тезисы доклада

Конференция 16th International Conference on Microwave and High Frequency Heating
18-21 сент. 2017 , Delft
Сборник 16th International Conference on Microwave and High Frequency Heating AMPERE 2017, Delft, The Netherlands, September 18-21, 2017
Сборник, TU. Delft.2017.
Вых. Данные Год: 2017, Номер статьи : 3, Страниц :
Ключевые слова Catalyst; Ethane oxidative dehydrogenation; Microwave heating
Авторы Bolotov V. 1,2 , Chesnokov V. 1 , Tanashev Yy.. 1 , Parmon V. 1,2
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Lavrentieva 5, 630090, Novosibirsk, Russia
2 Novosibirsk National Research State University, Novosibirsk-90, 2 Pirogova Str., 630090, Novosibirsk, Russia

Информация о финансировании (1)

1 Российский научный фонд 17-73-30032

Реферат: The oxidative dehydrogenation of ethane (ODE) to produce ethylene is an attractive alternative for petrochemical industry. Compared with a steam cracking, catalytic cracking and catalytic dehydrogenation, ODE is thermodynamically favored, and can be performed at lower reaction temperature without formation of coke. The main problem of ODE is usually a moderate selectivity of respective catalysts due to high reactivity of ethylene formed at high reaction temperature (> 600 °C). To increase selectivity of ODE, parallel and consecutive deep oxidation of ethylene performed via a homogeneous mechanism should be inhibited (quenched). The selective microwave (MW) heating of a catalyst as compared with a conventional heating allows the creation of conditions where a temperature gradient between “hot” catalyst and “cold” reactor volume is considerable. It is supposed that application of MW can perform effective quenching of the target ODE product. This paper presents the results of high temperature ODE under conventional and MW heating of the CeO2 – ZrO2 – BaO and BaCl2 – TiO2 – SnO2 catalysts.
Библиографическая ссылка: Bolotov V. , Chesnokov V. , Tanashev Y. , Parmon V.
The Oxidative Dehydrogenation of Ethane: Convectional vs Microwave Heating of Catalysts
В сборнике 16th International Conference on Microwave and High Frequency Heating AMPERE 2017, Delft, The Netherlands, September 18-21, 2017. – TU., 2017. Scopus РИНЦ
Идентификаторы БД:
Scopus: 2-s2.0-85065888080
РИНЦ: 39001633
Цитирование в БД: Пока нет цитирований