Synthesis of Highly Dispersed 2D Aluminum Cobalt Oxyhydroxide Compounds Based on Microwave-Activation Products of Crystalline Gibbsite Full article
| Journal |
Inorganic Materials
ISSN: 0020-1685 , E-ISSN: 1608-3172 |
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| Output data | Year: 2019, Volume: 55, Number: 4, Pages: 380-389 Pages count : 10 DOI: 10.1134/S0020168519040162 | ||||
| Tags | bent highly dispersed 2D aluminum cobalt compounds; crystalline gibbsite; microwave-activated gibbsite | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0004 |
Abstract:
We have studied interaction between the microwave activation product of gibbsite and an aqueous cobalt nitrate solution at room temperature, atmospheric pressure, and pH 8.0 ± 0.3. The results demonstrate that, under such conditions, the reaction in the near-surface region of the microwave-activated gibbsite particles leads to the formation of an aluminum cobalt oxyhydroxide with fragments of spinel structure and the composition Со2.3Al0.7O4, and a
Со6 – xAl2 – x(OH)1.5 · 3.5H2O (0 ≤ x ≤ 1) nonstoichiometric hydrotalcite. The morphology of such compounds is determined by 2D nanoparticles in the form of bent sheets 2–5 nm in thickness and 500 nm or more in length. After calcination at 500°C, the composition of the reaction products corresponds to the aluminum cobalt oxide Со2.3Al0.7O4 with the spinel structure.
Cite:
Zhuzhgov A.V.
, Krivoruchko O.P.
, Larina T.V.
, Ishchenko A.V.
, Isupova L.A.
Synthesis of Highly Dispersed 2D Aluminum Cobalt Oxyhydroxide Compounds Based on Microwave-Activation Products of Crystalline Gibbsite
Inorganic Materials. 2019. V.55. N4. P.380-389. DOI: 10.1134/S0020168519040162 WOS Scopus РИНЦ AN OpenAlex
Synthesis of Highly Dispersed 2D Aluminum Cobalt Oxyhydroxide Compounds Based on Microwave-Activation Products of Crystalline Gibbsite
Inorganic Materials. 2019. V.55. N4. P.380-389. DOI: 10.1134/S0020168519040162 WOS Scopus РИНЦ AN OpenAlex
Original:
Жужгов А.В.
, Криворучко О.П.
, Ларина Т.В.
, Ищенко А.В.
, Исупова Л.А.
Синтез 2D-высокодисперсных алюмокобальтовых оксигидроксидных соединений на основе продуктов СВЧ-активации кристаллического гиббсита
Неорганические материалы. 2019. Т.55. №4. С.411-420. DOI: 10.1134/S0002337X1904016X РИНЦ OpenAlex
Синтез 2D-высокодисперсных алюмокобальтовых оксигидроксидных соединений на основе продуктов СВЧ-активации кристаллического гиббсита
Неорганические материалы. 2019. Т.55. №4. С.411-420. DOI: 10.1134/S0002337X1904016X РИНЦ OpenAlex
Dates:
| Submitted: | Aug 21, 2018 |
| Accepted: | Oct 31, 2018 |
| Published print: | Apr 1, 2019 |
| Published online: | Jun 5, 2019 |
Identifiers:
| Web of science: | WOS:000470331200011 |
| Scopus: | 2-s2.0-85066954482 |
| Elibrary: | 41647812 |
| Chemical Abstracts: | 2019:1119994 |
| OpenAlex: | W2973459885 |