N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2019, Volume: 60, Number: 3, Pages: 343-354 Pages count : 12 DOI: 10.1134/S0023158419030030 | ||
| Tags | activity; copper state; Cu-containing layered double hydroxides; N-methylation; p-anisidine | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0004 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
Abstract:
Cu-containing layered double hydroxides with different Cu : Al ratios are synthesized by co-precipitation using a mixture of hydroxide and sodium carbonate as a precipitation agent. The influence of the precipitation agent concentration on the formation of the hydrotalcite phase was studied by thermal analysis and X-ray diffraction. The surface of the obtained samples after calcination at 450°C and their subsequent reduction at 300°C in hydrogen, was characterized by
X-ray photoelectron spectroscopy and transmission electron microscopy. The synthesized catalysts were tested in the reaction of N-methylation of p-anisidine with methanol in an autoclave reactor to produce N-methyl-p-anisidine. The influence of the Cu : Al ratio in them on the catalytic activity and selectivity was studied.
Cite:
Bukhtiyarova M.V.
, Nuzhdin A.L.
, Kardash T.Y.
, Bukhtiyarov A.V.
, Gerasimov E.Y.
, Romanenko A.V.
N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides
Kinetics and Catalysis. 2019. V.60. N3. P.343-354. DOI: 10.1134/S0023158419030030 WOS Scopus РИНЦ ANCAN OpenAlex
N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides
Kinetics and Catalysis. 2019. V.60. N3. P.343-354. DOI: 10.1134/S0023158419030030 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Бухтиярова М.С.
, Нуждин А.Л.
, Кардаш Т.Ю.
, Бухтияров А.В.
, Герасимов Е.Ю.
, Романенко А.В.
N-метилирование пара-анизидина на катализаторах на основе Cu-содержащих слоистых двойных гидроксидов
Кинетика и катализ. 2019. Т.60. №3. С.364-376. DOI: 10.1134/S0453881119030031 РИНЦ OpenAlex
N-метилирование пара-анизидина на катализаторах на основе Cu-содержащих слоистых двойных гидроксидов
Кинетика и катализ. 2019. Т.60. №3. С.364-376. DOI: 10.1134/S0453881119030031 РИНЦ OpenAlex
Dates:
| Submitted: | Sep 4, 2018 |
| Accepted: | Jan 15, 2019 |
| Published print: | May 1, 2019 |
| Published online: | Jun 18, 2019 |
Identifiers:
| Web of science: | WOS:000472087300012 |
| Scopus: | 2-s2.0-85065440899 |
| Elibrary: | 41622620 |
| Chemical Abstracts: | 2019:1219352 |
| Chemical Abstracts (print): | 172:130128 |
| OpenAlex: | W2950237178 |