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Hydrogenation of Furfural to 2-Methylfuran over Ni-Mo2C/γ-Al2O3 Catalyst Conference Abstracts

Conference 11th International Conference on Energy Planning, Energy Saving, Environmental Education
25-27 May 2019 , Рим
Source 11th International Conference on Energy Planning, Energy Saving, Environmental Education
Compilation, 2019.
Output data Year: 2019, Pages: 189-196 Pages count : 7
Tags biomass, furfural, 2-methylfuran, fuel additive, hydrogenation, carbide catalyst
Authors Smirnov Andrey A. 1,2 , Shilov Ivan N. 1,2 , Saraev Andrey A. 1,2 , Kauchev Vasily V. 1,2 , Bulavchenko Olga A. 1,2 , Zavarukhin Sergei G. 2,3 , Yakovlev Vadim A. 1,2
Affiliations
1 Novosibirsk State University, 630090, Pirogova Street 2, Novosibirsk, RUSSIA
2 Federal Research Center Boreskov Institute of Catalysis, 630090, Pr. Lavrentieva 5, Novosibirsk, RUSSIA
3 Novosibirsk State Technical University, 630073, Prospekt K. Marksa 20, Novosibirsk, RUSSIA

Funding (1)

1 The Ministry of Education and Science of the Russian Federation 14.575.21.0171 (RFMEFI57517X0171)

Abstract: The current study focuses on the synthesis of a new supported catalyst by impregnation of the γAl2O3 solution of Ni and Mo salts and citric acid as carbon resource with the following temperature programmed treatment. Characterization of catalyst composition was performed using XANES/EXAFS method shown the presence of molybdenum carbide and metallic nickel. The oxide form of Mo and Ni were also detected. The supported catalyst was investigated in the hydrogenation reaction of furfural. The free-solution furfural conversion was carried out at a temperature of 160-260 °C and a hydrogen pressure of 5.0 MPa in a fixed bed reactor. The main hydrogenation products were furfuryl alcohol and 2-methylfuran. It was shown that 2-methylfuran formation increases with the reaction temperature and reaches around 75-80 %. High temperature leads to fast catalyst deactivation due to polymer formation on its surface.
Cite: Smirnov A.A. , Shilov I.N. , Saraev A.A. , Kauchev V.V. , Bulavchenko O.A. , Zavarukhin S.G. , Yakovlev V.A.
Hydrogenation of Furfural to 2-Methylfuran over Ni-Mo2C/γ-Al2O3 Catalyst
In compilation 11th International Conference on Energy Planning, Energy Saving, Environmental Education. 2019. – C.189-196.
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Citing: Пока нет цитирований