An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine | Sciact - CRIS-system of Boreskov Institute of Catalysis

An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine Full article

Journal

Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779

Output data

Year: 2019, Volume: 60, Number: 6, Pages: 909-918 Pages count : 10 DOI: 10.1134/S0022476619060052

Tags

DFT; electronic structure; NEXAFS; platinum(II) complexes; radical anion N-phenyl-obenzosemiquinondiimine; redox-active ligands; XPS

Authors

Ivanova T.M. ¹ , Sidorov A.A. ¹ , Mazalov L.N. ^2,3 , Fedorenko A.D. ² , Kiskin M.A. ¹ , Savilov S.V. ^1,4 , Lunin V.V. ^1,4 , Novotortsev V.M. ¹ , Eremenko I.L. ¹ , Kalinkin A.V. ⁵ , Fedoseeva Yu.V. ² , Okotrub A.V. ^2,3

Affiliations

1	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation
3	Novosibirsk State University, Novosibirsk, Russian Federation
4	Moscow State University, Moscow, Russian Federation
5	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russian Federation

Funding (3)

1	Russian Science Foundation	14-23-00176
2	Russian Foundation for Basic Research	16-03-00047 (АААА-А16-116020110081-3)
3	Ministry of Science and Higher Education of the Russian Federation

The electronic structure of mono- and binuclear platinum complexes with N-phenyl-o benzosemiquinondiimine ligands was studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, and the density functional theory. The oxidation state of the central platinum ion corresponds to that of Pt(II). Upon the transition from the trans-complex 1 to the cis-complex 2 and to the binuclear complex 3, the electron density on platinum and nitrogen atoms decreases thus testifying the participation of platinum and nitrogen atoms in the oxidation processes and in the formation of binuclear complex 3. © 2019, Pleiades Publishing, Inc.

Ivanova T.M. , Sidorov A.A. , Mazalov L.N. , Fedorenko A.D. , Kiskin M.A. , Savilov S.V. , Lunin V.V. , Novotortsev V.M. , Eremenko I.L. , Kalinkin A.V. , Fedoseeva Y.V. , Okotrub A.V.
An X-ray Spectral Study of the Electronic Structure of Non-Innocent Mono- and Binuclear Platinum Complexes with N-Phenyl-o-Benzosemiquinonediimine
Journal of Structural Chemistry. 2019. V.60. N6. P.909-918. DOI: 10.1134/S0022476619060052 WOS Scopus РИНЦ AN OpenAlex

Иванова Т.М. , Сидоров А.А. , Мазалов Л.Н. , Федоренко А.Д. , Кискин М.А. , Савилов С.В. , Лунин В.В. , Новоторцев В.М. , Еременко И.Л. , Калинкин А.В. , Федосеева Ю.В. , Окотруб А.В.
Рентгеноспектральное изучение электронного строения неинноцентных моно- и биядерных комплексов платины с N-фенил-о-бензосемихинондиимином
Журнал структурной химии. 2019. Т.60. №6. С.948-958. DOI: 10.26902/JSC_id40541RSCI РИНЦ OpenAlex

Submitted:	Sep 24, 2018
Accepted:	Jan 17, 2019
Published print:	Jun 1, 2019
Published online:	Jul 4, 2019

Web of science:	WOS:000474373600005
Scopus:	2-s2.0-85068776766
Elibrary:	41643081
Chemical Abstracts:	2019:1330360
OpenAlex:	W2953446766

DB	Citing
Scopus	1
Web of science	1
Elibrary	1
OpenAlex	1