Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes Conference Abstracts

Conference

27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds”
02-06 Oct 2017 , Нижний Новоород

Source

27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds” : Book of Abstracts
Compilation, Nizhny Novgorod.2017. 602 c. РИНЦ

Output data

Year: 2017, Pages: Y37 Pages count : 1

Authors

Tkachenko N.V. ^1,2 , Lyakin O.Yu. ^1,2 , Talsi E.P. ^1,2 , Bryliakov K.P. ^1,2

Affiliations

1	Novosibirsk State University, Novosibirsk, RUSSIA
2	Boreskov Institute of Catalysis SB RAS, Novosibirsk, RUSSIA

Funding (1)

Russian Foundation for Basic Research

17-03-00991

In this work, a series of chiral iron(III) aminopyridine complexes have been prepared and tested in the aerobic oxidative coupling of substituted β-naphthols. Upon 1 mol. % catalyst loadings, these complexes ensure moderate to good yield of the corresponding BINOLs (up to 94 % within 24 h), having up to 55 % optical purity.

Tkachenko N.V. , Lyakin O.Y. , Talsi E.P. , Bryliakov K.P.
Asymmetric Oxidative Coupling of β-Naphthols in the Presence of Chiral Aminopyridine Iron Complexes
In compilation 27th International Chugaev Conference on Coordination Chemistry and 4th Young Conference School “Physicochemical Methods in the Chemistry of Coordination Compounds” : Book of Abstracts. 2017. – C.Y37.

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