Recent Advances in Catalytic Asymmetric Dihydroxylation of Olefins | Sciact - CRIS-система Института катализа

Recent Advances in Catalytic Asymmetric Dihydroxylation of Olefins Обзор

Журнал

Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837

Вых. Данные

Год: 2019, Том: 88, Номер: 11, Страницы: 1094–1103 Страниц : 10 DOI: 10.1070/RCR4904

Ключевые слова

ENANTIOSELECTIVE CIS-DIHYDROXYLATION; TRANS-DIHYDROXYLATION; HYDROGEN-PEROXIDE; NONHEME IRON; ALKENES; DIBORATION; EPOXIDATION; HYDROLYSIS; OXIDATION; CHEMO

Авторы

Ottenbacher Roman V. ^1,2 , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Novosibirsk State University
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0005
2	Российский фонд фундаментальных исследований	16-29-10666

Asymmetric dihydroxylation of olefinic groups is an extremely important synthetic transformation which has been widely utilized to obtain optically pure pharmaceuticals and other fine chemical products. In recent years,catalyst systems for the asymmetric C=C dihydroxylations have attracted significant interest, the major research efforts being focused on designing environmentally benign catalyst systems. This mini-review summarizes recent progress in the field, surveying both novel, less toxic modifications of the classical osmium-based catalysts, and the highly efficient and enantioselective non-osmium catalyst systems. The bibliography includes 50 references.

Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Recent Advances in Catalytic Asymmetric Dihydroxylation of Olefins
Russian Chemical Reviews. 2019. V.88. N11. P.1094–1103. DOI: 10.1070/RCR4904 WOS Scopus РИНЦ OpenAlex CAPlus

Поступила в редакцию:	5 июн. 2019 г.
Опубликована online:	31 окт. 2019 г.
Опубликована в печати:	30 нояб. 2019 г.

≡ Web of science:	WOS:000517796400002
≡ Scopus:	2-s2.0-85076591702
≡ РИНЦ:	43229757
≡ OpenAlex:	W2969860927
≡ Chemical Abstracts:	2020:376437

≡ Scopus	26	Сбор данных от 22.02.2026
≡ Web of science	28	Сбор данных от 20.02.2026
≡ РИНЦ	22	Сбор данных от 22.02.2026
≡ OpenAlex	29	Сбор данных от 22.02.2026