A Study on the Oxidative Coupling of Methane over La2-xMgxTiO4 Catalysts Full article
Conference |
16th International Conference of Students and Young Scientists on Prospects of Fundamental Sciences Development 23-26 Apr 2019 , Томск |
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Journal |
IOP Conference Series - Materials Science and Engineering
ISSN: 1757-8981 |
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Output data | Year: 2019, Volume: 597, Number: 1, Article number : 012026, Pages count : 5 DOI: 10.1088/1757-899x/597/1/012026 | ||
Tags | Catalyst selectivity; Magnesium compounds; Methane; Perovskite; Specific surface area; Titanium dioxide; X ray diffraction analysis | ||
Authors |
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Affiliations |
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Funding (1)
1 | Federal Agency for Scientific Organizations | 0303-2016-0004 |
Abstract:
La2-xMgxTiО5-δ samples with different content of Mg and La were synthesized by the precipitation from a mixed solution of Mg(NO3)2 and La(NO3)3 in the presence of TiO2 suspension. The samples were characterized using X-ray diffractometry, mercury porosimetry, and BET techniques. Specific surface area of the samples ranges from 0.1 to
4.17 m2/g, and pore volume, from 0.005 to 0.023 cm3/g. Activity and selectivity of the samples in the oxidative
condensation of methane (OCM) were measured using a fixed catalyst bed flow quartz reactor. It was demonstrated that samples with x ≤ 0.6 showed the highest activity toward OCM reaction. This can be explained by a high content of the main active phase (La,Mg)2TiO5-δ with the layered perovskite structure and a sufficient specific surface area.
Cite:
Ivanova Y.
, Petrov R.
, Arhipova M.
, Reshetnikov S.
, Isupova L.
A Study on the Oxidative Coupling of Methane over La2-xMgxTiO4 Catalysts
IOP Conference Series - Materials Science and Engineering. 2019.
V.597. N1. 012026
:1-5. DOI: 10.1088/1757-899x/597/1/012026
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A Study on the Oxidative Coupling of Methane over La2-xMgxTiO4 Catalysts
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Full text from publisher
Dates:
Submitted: | Jul 26, 2019 |
Published online: | Aug 23, 2019 |
Identifiers:
Scopus: | 2-s2.0-85073601030 |
Elibrary: | 41689919 |
Chemical Abstracts: | 2019:2286621 |
OpenAlex: | W2969766119 |
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