Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst Full article
| Journal |
Energies
ISSN: 1996-1073 |
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| Output data | Year: 2019, Volume: 12, Number: 18, Article number : 3577, Pages count : 10 DOI: 10.3390/en12183577 | ||||
| Tags | formic acid decomposition; hydrogen production; CuO-CeO2/γ-Al2O3; multifuel processor; copper catalyst; oxygenates; fuel cell | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0011 |
Abstract:
Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pressure, at 200–300 °C, N2:HCOOH = 75:25 vol.% and flow rate 3500–35,000 h−1 with H2 yield of 98%, wherein outlet CO concentration is below the equilibrium data (<0.5 vol.%). The copper-ceria catalyst proved to be promising for multifuel processor application, and the H2 generation from dimethoxymethane, methanol, dimethyl ether and formic acid on the same catalyst for fuel cell supply.
Cite:
Pechenkin A.
, Badmaev S.
, Belyaev V.
, Sobyanin V.
Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst
Energies. 2019.
V.12. N18. 3577
:1-10. DOI: 10.3390/en12183577
WOS
Scopus
РИНЦ
AN
OpenAlex
Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO2/γ-Al2O3 Catalyst
Energies. 2019.
V.12. N18. 3577
:1-10. DOI: 10.3390/en12183577
WOS
Scopus
РИНЦ
AN
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Aug 29, 2019 |
| Accepted: | Sep 12, 2019 |
| Published print: | Sep 19, 2019 |
| Published online: | Sep 19, 2019 |
Identifiers:
| Web of science: | WOS:000489101200173 |
| Scopus: | 2-s2.0-85072542374 |
| Elibrary: | 41639885 |
| Chemical Abstracts: | 2020:659274 |
| OpenAlex: | W2974719154 |