Protons Make Possible Heterolytic Activation of Hydrogen Peroxide over Zr-Based Metal-Organic Frameworks | Sciact - CRIS-system of Boreskov Institute of Catalysis

Protons Make Possible Heterolytic Activation of Hydrogen Peroxide over Zr-Based Metal-Organic Frameworks Full article

Journal

ACS Catalysis
ISSN: 2155-5435

Output data

Year: 2019, Volume: 9, Pages: 9699−9704 Pages count : 6 DOI: 10.1021/acscatal.9b02941

Tags

cyclohexene, epoxidation, heterogeneous catalysis, hydrogen peroxide, metal−organic frameworks, UiO, zirconium

Authors

Maksimchuk Nataliya V. ^1,2 , Lee Ji Sun ³ , Solovyeva Marina V. ^1,2 , Cho Kyung Ho ³ , Shmakov Aleksandr N. ¹ , Chesalov Yuriy A. ^1,2 , Chang Jong-San ^3,4 , Kholdeeva Oxana A. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova str. 2, Novosibirsk 630090, Russia
3	Research Center for Nanocatalysts, Korea Research Institute of Chemical Technology, P.O. Box 107, Yuseong, Daejeon 305-600, Korea
4	Department of Chemistry, Sungkyunkwan University, Suwon 440-475, Korea

Funding (3)

1	Federal Agency for Scientific Organizations	0303-2016-0005
2	Russian Foundation for Basic Research	18-29-04022
3	Korea Research Institute of Chemical Technology	SK-1301

The catalytic performance of zirconium-based metal−organic frameworks (UiO-66, UiO-67, and MOF-801) in cyclohexene oxidation with aqueous hydrogen peroxide can be greatly improved by adding a source of protons directly into the reaction mixture. A blend of Zr-MOF and protons favors heterolytic activation of H2O2 and makes possible selective formation of epoxide and diol with negligible formation of allylic oxidation products. Additives of HClO4 suppress the rates of H2O2 decomposition over Zr-MOF and increase oxidant utilization efficiency. No structural changes occur in the acid-activated Zr-MOF. The catalyst does not suffer metal leaching, reveals a truly heterogeneous nature of the catalysis, and can be recovered and reused.

Maksimchuk N.V. , Lee J.S. , Solovyeva M.V. , Cho K.H. , Shmakov A.N. , Chesalov Y.A. , Chang J-S. , Kholdeeva O.A.
Protons Make Possible Heterolytic Activation of Hydrogen Peroxide over Zr-Based Metal-Organic Frameworks
ACS Catalysis. 2019. V.9. P.9699−9704. DOI: 10.1021/acscatal.9b02941 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 12, 2019
Accepted:	Aug 21, 2019
Published online:	Sep 25, 2019
Published print:	Nov 1, 2019

Web of science:	WOS:000494549700001
Scopus:	2-s2.0-85073166519
Elibrary:	41690518
Chemical Abstracts:	2019:1844667
Chemical Abstracts (print):	171:483103
OpenAlex:	W2975764505

DB	Citing
Scopus	46
Web of science	42
Elibrary	41
OpenAlex	47