Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural Full article
| Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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| Output data | Year: 2019, Volume: 11, Number: 3, Pages: 216-223 Pages count : 8 DOI: 10.1134/s2070050419030103 | ||||
| Tags | furfural, furfuryl alcohol, hydrogenation, copper–iron catalysts | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | The Ministry of Education and Science of the Russian Federation | 14.575.21.0171 (RFMEFI57517X0171) |
Abstract:
Cu- and Fe-containing catalysts are studied in the reaction of selective hydrogenation of furfural to furfuryl alcohol (FA). The catalysts are prepared by alloying the respective metal nitrates and reduced before the reaction directly in the reactor at 250°C. The process is conducted in a batch reactor at 150°C and 6.0 MPa of hydrogen pressure. It is shown that the most active catalyst is Cu20Fe66Al14, the furfural conversion and selectivity toward FA in the presence of which are 96 and 97 mol %, respectively. Inside a continuous-flow reactor in the presence of this catalyst, 100% furfural conversion can be attained at a selectivity toward FA of up to 95 mol % at 160°C and 5 MPa of hydrogen pressure. The resulting catalyst remains active for 30 h of continuous operation. The high activity of the copper–iron catalyst is likely due to the presence of stabilized finely divided copper particles in it.
Cite:
Selishcheva S.A.
, Smirnov A.A.
, Fedorov A.V.
, Ermakov D.Y.
, Gulyaeva Y.K.
, Yakovlev V.A.
Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural
Catalysis in Industry. 2019. V.11. N3. P.216-223. DOI: 10.1134/s2070050419030103 WOS Scopus РИНЦ OpenAlex
Production of Furfuryl Alcohol in the Presence of Copper-Containing Catalysts in the Selective Hydrogenation of Furfural
Catalysis in Industry. 2019. V.11. N3. P.216-223. DOI: 10.1134/s2070050419030103 WOS Scopus РИНЦ OpenAlex
Original:
Селищева С.А.
, Смирнов А.А.
, Федоров А.В.
, Ермаков Д.Ю.
, Гуляева Ю.К.
, Яковлев В.А.
Получение фурфурилового спирта в присутствии медь-железосодержащих катализаторов в реакции селективного гидрирования фурфурола
Катализ в промышленности. 2019. Т.19. №2. С.95-103. DOI: 10.18412/1816-0387-2019-2-95-103RSCI РИНЦ AN OpenAlex
Получение фурфурилового спирта в присутствии медь-железосодержащих катализаторов в реакции селективного гидрирования фурфурола
Катализ в промышленности. 2019. Т.19. №2. С.95-103. DOI: 10.18412/1816-0387-2019-2-95-103RSCI РИНЦ AN OpenAlex
Dates:
| Submitted: | Nov 14, 2018 |
| Accepted: | Jan 17, 2019 |
| Published print: | Jul 1, 2019 |
| Published online: | Sep 16, 2019 |
Identifiers:
| Web of science: | WOS:000486336600005 |
| Scopus: | 2-s2.0-85073189369 |
| Elibrary: | 41694067 |
| OpenAlex: | W2974618516 |