Highly Active CuFeAl-containing Catalysts for Selective Hydrogenation of Furfural to Furfuryl Alcohol | Sciact - CRIS-система Института катализа

Highly Active CuFeAl-containing Catalysts for Selective Hydrogenation of Furfural to Furfuryl Alcohol Научная публикация

Журнал

Catalysts
ISSN: 2073-4344

Вых. Данные

Год: 2019, Том: 9, Номер: 10, Номер статьи : 816, Страниц : 20 DOI: 10.3390/catal9100816

Ключевые слова

furfural; furfuryl alcohol; CuFe-containing catalyst; hydrogenation

Авторы

Selishcheva Svetlana A. ^1,2 , Smirnov Andrey A. ^1,2 , Fedorov Alexander V. ^1,2 , Bulavchenko Olga A. ^1,2 , Saraev Andrey A. ^1,2 , Lebedev Maksim Yu. ^1,2 , Yakovlev Vadim A. ^1,2

Организации

1	Scientific and Education Center of Energy Efficient Catalysis, Novosibirsk State University, Pirogova Str., 1, 630090 Novosibirsk, Russia
2	Department of Catalytic Processes of Fine and Bioorganic Synthesis, Federal Research Center Boreskov Institute of Catalysis, Pr. Akad. Lavrentieva, 5, 630090 Novosibirsk, Russia

Информация о финансировании (1)

Министерство образования и науки Российской Федерации

14.575.21.0171 (RFMEFI57517X0171)

CuFe-containing catalysts with different copper oxide content were prepared by fusion of metal salts. The obtained catalyst showed high activity in the hydrogenation of furfural to furfuryl alcohol (FA) in the batch reactor in the presence of isopropanol as a solvent at a temperature of 100 ◦C and a hydrogen pressure of 6.0 MPa. The yield of FA and furfural conversion are 97% and 98%, respectively. In the solvent-free reaction in the flow-type reactor; the most active catalyst Cu20Fe66Al14 leads to the 96% formation of FA with 100% conversion of furfural at liquid hourly space velocity (LHSV) = 1 h−1; 160 ◦C and a hydrogen pressure of 5.0 MPa during 30 h. According to the X-ray diffraction (XRD) method, the active component of the spent and fresh Cu20Fe66Al14 catalyst is the same and is represented by metallic copper and Fe3O4-type spinel. Using different methods, the formation of active sites was investigated.

Selishcheva S.A. , Smirnov A.A. , Fedorov A.V. , Bulavchenko O.A. , Saraev A.A. , Lebedev M.Y. , Yakovlev V.A.
Highly Active CuFeAl-containing Catalysts for Selective Hydrogenation of Furfural to Furfuryl Alcohol

Catalysts. 2019. V.9. N10. 816 :1-20. DOI: 10.3390/catal9100816 WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	30 авг. 2019 г.
Принята к публикации:	27 сент. 2019 г.
Опубликована online:	28 сент. 2019 г.

Web of science:	WOS:000498266100032
Scopus:	2-s2.0-85073593795
РИНЦ:	41688789
Chemical Abstracts:	2019:2002927
OpenAlex:	W2978695135

БД	Цитирований
Scopus	19
Web of science	18
OpenAlex	22