Design and Characterization of Nanocomposite Catalysts for Biofuel Conversion into Syngas and Hydrogen in Structured Reactors and Membranes Review
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2019, Volume: 60, Number: 5, Pages: 582-605 Pages count : 24 DOI: 10.1134/S0023158419050082 | ||||
| Tags | nanocrystalline mixed oxides, fluorite, perovskite, spinel structures, synthesis, characterization of the structure, surface, mobility and reactivity of oxygen, catalysis of biofuel conversion into syngas, mechanism, structured catalysts and catalytic membranes, performance and stability, mathematical modeling | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0013 |
| 2 | Russian Science Foundation | 18-73-10167 |
Abstract:
This review considers the problems associated with the development and operation of highly active and stable structured catalysts for biogas/biofuel conversion into syngas and hydrogen based on nanocrystalline oxides with fluorite, perovskite, and spinel structures and their nanocomposites promoted by nanoparticles of platinum group metals and alloys based on nickel. The design of these catalysts is based on finding the relationships between the methods of their synthesis, composition, real structure/microstructure, surface properties, and oxygen mobility and reactivity largely determined by the metal–support interaction. This requires the use of modern structural, spectroscopic, kinetic methods, and mathematical modeling. Thin layers of optimized catalysts deposited on structured heat-conducting supports demonstrated high activity and resistance to carbonization in the processes of biogas and biofuels conversion into syngas, and catalysts deposited on asymmetric ceramic membranes with mixed ionic–electronic conductivity allowed oxygen or hydrogen to be separated from complex mixtures with 100% selectivity.
Cite:
Sadykov V.A.
, Simonov M.N.
, Bespalko Y.N.
, Bobrova L.N.
, Eremeev N.F.
, Arapova M.V.
, Smal’ E.A.
, Mezentseva N.V.
, Pavlova S.N.
Design and Characterization of Nanocomposite Catalysts for Biofuel Conversion into Syngas and Hydrogen in Structured Reactors and Membranes
Kinetics and Catalysis. 2019. V.60. N5. P.582-605. DOI: 10.1134/S0023158419050082 WOS Scopus РИНЦ AN OpenAlex
Design and Characterization of Nanocomposite Catalysts for Biofuel Conversion into Syngas and Hydrogen in Structured Reactors and Membranes
Kinetics and Catalysis. 2019. V.60. N5. P.582-605. DOI: 10.1134/S0023158419050082 WOS Scopus РИНЦ AN OpenAlex
Original:
Садыков В.А.
, Симонов М.Н.
, Беспалко Ю.Н.
, Боброва Л.Н.
, Еремеев Н.Ф.
, Арапова М.В.
, Смаль Е.А.
, Мезенцева Н.В.
, Павлова С.Н.
Дизайн и характеризация нанокомпозитных катализаторов трансформации биотоплив в синтез-газ и водород в структурированных реакторах и мембранах
Кинетика и катализ. 2019. Т.60. №5. С.588-611. DOI: 10.1134/S0453881119050095 РИНЦ OpenAlex
Дизайн и характеризация нанокомпозитных катализаторов трансформации биотоплив в синтез-газ и водород в структурированных реакторах и мембранах
Кинетика и катализ. 2019. Т.60. №5. С.588-611. DOI: 10.1134/S0453881119050095 РИНЦ OpenAlex
Dates:
| Submitted: | Mar 20, 2019 |
| Accepted: | Apr 8, 2019 |
| Published print: | Sep 1, 2019 |
| Published online: | Oct 7, 2019 |
Identifiers:
| Web of science: | WOS:000490016900004 |
| Scopus: | 2-s2.0-85073191313 |
| Elibrary: | 41694617 |
| Chemical Abstracts: | 2019:1920737 |
| OpenAlex: | W2979665536 |